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ABSTRACT:
SUBMITTER: Kutzky B
PROVIDER: S-EPMC3050386 | biostudies-literature | 2010 Dec
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20101218 Pt 1
The crystal structure of the title compound, [Rh(C(6)H(19)N(4))Cl(3)]Cl·0.5H(2)O, is isotypic with the previously reported Ru analogue. The structure contains two crystallographically independent [Rh(Htren)Cl(3)](+) cations with a facial tridentate coordination of the monoprotonated tren ligand [tren = tris-(2-amino-eth-yl)amine], leading to an overall distorted octahedral coordination environment around the Rh(III) atom. In one of the two cations, the ethyl-ene groups of the two chelate rings a ...[more]