Browse
Submit Data
Databases
API
Help

Dataset Information

29 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

{4-Hy-droxy-N'-[(2E,3Z)-4-oxido-4-phenyl-but-3-en-2-yl-idene]benzo-hydra-zidato}diphenyl-tin(IV) methanol monosolvate.

ABSTRACT: Two independent diphenyl-tin mol-ecules and two independent methanol mol-ecules comprise the asymmetric unit of the title compound, [Sn(C(6)H(5))(2)(C(17)H(14)N(2)O(3))]·CH(3)OH. The Sn atom in each is five-coordinated by a tridentate ligand and the ipso-C atoms of the Sn-bound benzene substituents. The resulting C(2)N(2)O donor set defines a coordination geometry that is inter-mediate between trigonal-bipyramidal (TP) and square-pyramidal (SP), with one mol-ecule slightly tending towards TP and the other slightly towards SP. The mol-ecules differ in terms of the relative orientations of the terminal benzene rings [dihedral angles = 45.71 (18) and 53.98 (17)°] and of the Sn-bound benzene substituents [dihedral angles = 59.5 (2) and 45.77 (18)°, respectively]. The most prominent feature of the crystal packing is the formation of four-mol-ecule aggregates via O-H⋯O and O-H⋯N hydrogen bonds, in which the hy-droxy group is connected to a methanol mol-ecule which, in turn, is linked to a non-coordinating N atom. Weak C-H⋯π inter-actions also occur.

SUBMITTER: Affan MA

PROVIDER: S-EPMC3151954 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

{4-Hy-droxy-N'-[(2E,3Z)-4-oxido-4-phenyl-but-3-en-2-yl-idene]benzo-hydrazidato}dimethyl-tin(IV).

Project description:The Sn(IV) atom in the title compound, [Sn(CH(3))(2)(C(17)H(14)N(2)O(3))], is five-coordinated within a C(2)N(2)O donor set provided by the N,N,O-tridentate ligand and two methyl groups. The resultant coordination geometry is inter-mediate between trigonal-bipyramidal and square-pyramidal. In the crystal, supra-molecular zigzag chains propagating along the c- axis direction are mediated by O-H?O hydrogen bonds, and weak C-H?? inter-actions consolidate the packing.

| S-EPMC3151873 | biostudies-other

[2-Oxido-1-naphthaldehyde (2-hydroxy-benzo-yl)hydrazonato]diphenyl-tin(IV).

Project description:In the title compound, [Sn(C(6)H(5))(2)(C(18)H(12)N(2)O(3))], the Sn(IV) atom has a distorted trigonal-bipyramidal geometry. The Schiff base mol-ecule is coordinated to the Sn(IV) atom in a tridentate fashion via the azomethine N atom, the hydr-oxy O atom and the carbonyl O atom. The complex involves an intra-molecular O-H?N hydrogen bond.

| S-EPMC2971108 | biostudies-other

N'-(4-Diethyl-amino-2-hy-droxy-benzyl-idene)-4-(dimethyl-amino)-benzo-hydrazide methanol monosolvate.

Project description:The title compound, C(20)H(26)N(4)O(2)·CH(3)OH, was prepared by the reaction of 4-diethyl-amino-2-hy-droxy-benzaldehyde with 4-(dimethyl-amino)-benzohydrazide. The dihedral angle between the two benzene rings is 13.6 (3)° and an intra-molecular O-H⋯N hydrogen bond generates an S(6) ring. In the crystal, the hydrazone and methanol mol-ecules are linked through inter-molecular O-H⋯O and N-H⋯O hydrogen bonds, forming chains along a.

| S-EPMC3151952 | biostudies-literature

Hexa-?2-acetato-hexa-n-butyl-hexa-?3-oxido-tin(IV) toluene monosolvate.

Project description:The title compound, [Sn6(C4H9)6(CH3COO)6O6]·C7H8, has one half-toluene mol-ecule and one half-organotin mol-ecule in the asymmetric unit. The latter is situated about an inversion centre and belongs to the class of hexa-meric monoorganooxo-tin carboxyl-ates with a hexa-gonal prismatic or 'drum-like' motif of the central tin-oxygen core. Two Sn3O3 rings in a flat-chair conformation are linked via six Sn-O bonds and six bridging acetate groups. All Sn atoms have approximate octa-hedral coordination geometry. The Sn-O bonds which are trans to the alkyl group are significantly shorter than the others. One butyl group is disordered over two different sites, with occupancies of 0.9:0.1. Very large atomic displacement parameters of the toluene mol-ecule indicate an unresolvable disorder about the twofold axis.

| S-EPMC3588278 | biostudies-literature

(E)-4-Hy-droxy-N'-(2-hy-droxy-5-iodo-benzyl-idene)benzohydrazide methanol monosolvate.

Project description:In the title compound, C(14)H(11)IN(2)O(3)·CH(4)O, the dihedral angle between the benzene rings is 33.2 (3)°. The mol-ecule displays trans and anti conformations about the C=N and N-N bonds, respectively. There is an intra-molecular O-H⋯N(azomethine) hydrogen bond. Inter-molecular N-H⋯O and O-H⋯O hydrogen bonds consolidate mol-ecules into a three-dimensional architecture.

| S-EPMC3435718 | biostudies-literature

(+)-Chlorido[(1,2,3,4-?;?P)-2'-diphenyl-phosphanyl-2-diphenyl-phosphoryl-1,1'-binaphth-yl]rhodium(I) methanol monosolvate.

Project description:In the title complex, [RhCl(C(44)H(32)OP(2))]·CH(3)OH, the Rh(I) ion is coordinated by a naphthyl group of a partially oxidized 2,2'-bis-(diphenyl-phosphan-yl)-1,1'-binaphthyl (BINAP) ligand in a ?(4) mode, one P atom of the diphenyl-phosphanyl group and one Cl atom. The P=O group does not inter-act with the Rh(I) ion but accepts an O-H?O hydrogen bond from the methanol solvent mol-ecule.

| S-EPMC3297224 | biostudies-literature

Hexa-μ(2)-acetato-κO:O'-(azido-κN)bis-(methanol-κO)-μ(3)-oxido-trichromium(III) methanol monosolvate.

Project description:In the crystal structure of the title complex, [Cr(3)(CH(3)CO(2))(6)(N(3))O(CH(3)OH)(2)]·CH(3)OH, the trinuclear core has a central O atom; two methanol mol-ecules and an azide ion are coordinated to the Cr(III) atoms in the core. The three Cr(III) atoms form vertices of a nearly equilateral triangle. Each of the six acetate carboxyl-ate groups bridges a Cr-O-Cr fragment. In the crystal, the molecules inter-act with methanol solvent mol-ecules through O-H⋯O and O-H⋯N hydrogen bonds, forming a two-dimensional hydrogen-bonded network parallel to (100).

| S-EPMC3246918 | biostudies-literature

Di-n-but-yl[4-hy-droxy-N'-(3-meth-oxy-2-oxido-benzyl-idene-?O (2))benzo-hydrazidato-?(2) N,O]tin(IV).

Project description:In the title compound, [Sn(C4H9)2(C15H12N2O4)], the Sn(IV) atom is coordinated by the N, O and O' atoms from the tridentate Schiff base dianion in an overall cis-C2SnNO2 trigonal-bipyramidal geometry. Adjacent mol-ecules are linked by O-H?O hydrogen bonds, forming a chain running along [001].

| S-EPMC3885005 | biostudies-literature

μ-Oxido-bis-({2,2'-[o-phenylenebis(nitrilo-methylidyne)]diphenolato}iron(III)) methanol monosolvate dihydrate.

Project description:The title complex, [Fe(2)(C(20)H(14)N(2)O(2))(2)O]·CH(4)O·2H(2)O, is composed of μ-oxido-bridged ferric 2,2'-[o-phenylene-bis(nitrilo-methylidyne)]diphenolate (salphen) dimers, one methanol mol-ecule and two H(2)O mol-ecules. Each iron(III) ion, surrounded by two coordinating N and O atoms from the salphen ligand and one bridging O atom, shows a five-coordinate square-pyramidal geometry. One of the two solvent water mol-ecules is disordered over three positions with occupancies of 0.44 (1), 0.37 (1) and 0.19 (1).

| S-EPMC3007942 | biostudies-literature

N'-(2-Bromo-5-hy-droxy-4-meth-oxy-benzyl-idene)-3,5-dihy-droxy-benzo-hydrazide methanol monosolvate.

Project description:In the crystal structure of the title compound, C(15)H(13)BrN(2)O(5)·CH(3)OH, the methanol solvent mol-ecule links symmetry-related mol-ecules through O-H?O and N-H?O hydrogen bonds. Further inter-molecular O-H?O hydrogen bonds link symmetry-related mol-ecules, leading to the formation of a three-dimensional network. Two of the H atoms involved in hydrogen bonding are disordered. The dihedral angle between the rings is 5.64?(14)°.

| S-EPMC3099906 | biostudies-other

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data