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Poly[trans-diaquabis-[?(2)-2-(pyridin-3-yl)acetato-?N:O]-zinc].

ABSTRACT: In the title coordination polymer, [Zn(C(7)H(6)NO(2))(2)(H(2)O)(2)](n), the Zn(II) cation is located on an inversion center and is coordinated by four pyridyl-acetate anions and two water mol-ecules in a distorted ZnN(2)O(4) octa-hedral geometry. The pyridine-N and carboxyl-ate-O atoms of the pyridyl-acetate anion connect to two Zn(II) cations, forming a two-dimensional polymeric complex extending parallel to (212). Inter-molecular O-H?O and weak C-H?O hydrogen bonding is present in the crystal structure.

SUBMITTER: Li YH

PROVIDER: S-EPMC3201260 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

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Poly[trans-diaquabis-[μ(2)-2-(pyridin-3-yl)acetato-κN:O]-zinc].

Li Yue-Hua YH Du Lin L Li Zong-Ze ZZ Zhao Qi-Hua QH

Acta crystallographica. Section E, Structure reports online 20110930 Pt 10

In the title coordination polymer, [Zn(C(7)H(6)NO(2))(2)(H(2)O)(2)](n), the Zn(II) cation is located on an inversion center and is coordinated by four pyridyl-acetate anions and two water mol-ecules in a distorted ZnN(2)O(4) octa-hedral geometry. The pyridine-N and carboxyl-ate-O atoms of the pyridyl-acetate anion connect to two Zn(II) cations, forming a two-dimensional polymeric complex extending parallel to (212). Inter-molecular O-H⋯O and weak C-H⋯O hydrogen bonding is present in the crystal ...[more]

PMID: 22058713

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