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Aqua-(cyanido-?C){6,6'-dimeth-oxy-2,2'-[o-phenyl-enebis(nitrilo-methanylyl-idene)]diphenolato-?O,N,N',O}cobalt(III) acetonitrile monosolvate.

ABSTRACT: In the title complex, [Co(C(22)H(18)N(2)O(4))(CN)(H(2)O)]·CH(3)CN, the Co(III) ion is six-coordinated in a distorted octa-hedral environment defined by two N atoms and two O atoms from a salen ligand in the equatorial plane and one O atom from a water mol-ecule and one C atom from a cyanide group at the axial positions. O-H?O hydrogen bonds connect adjacent complex mol-ecules into dimers. C-H?N hydrogen bonds and ?-? inter-actions between the benzene rings [centroid-centroid distances = 3.700?(2) and 3.845?(2)?Å] are also present.

SUBMITTER: Lin Y

PROVIDER: S-EPMC3212260 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

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Aqua-(cyanido-κC){6,6'-dimeth-oxy-2,2'-[o-phenyl-enebis(nitrilo-methanylyl-idene)]diphenolato-κO,N,N',O}cobalt(III) acetonitrile monosolvate.

Lin Yang Y Li Guang-Ming GM Chen Peng P Yan Peng-Fei PF Hou Guang-Feng GF

Acta crystallographica. Section E, Structure reports online 20110730 Pt 8

In the title complex, [Co(C(22)H(18)N(2)O(4))(CN)(H(2)O)]·CH(3)CN, the Co(III) ion is six-coordinated in a distorted octa-hedral environment defined by two N atoms and two O atoms from a salen ligand in the equatorial plane and one O atom from a water mol-ecule and one C atom from a cyanide group at the axial positions. O-H⋯O hydrogen bonds connect adjacent complex mol-ecules into dimers. C-H⋯N hydrogen bonds and π-π inter-actions between the benzene rings [centroid-centroid distances = 3.700 (2 ...[more]

PMID: 22090917

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