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Poly[?(2)-aqua-aqua-?(5)-naphthalene-2,7-disulfonato-strontium].


ABSTRACT: In the crystal structure of the polymeric title compound, [Sr(C(10)H(6)O(6)S(2))(H(2)O)(2)](n), the naphthalene-2,7-disulfonate dianion uses one -SO(3) unit to bind to two Sr(II) cations and the other -SO(3) unit to bind to three Sr(II) cations; of the two coordinated water mol-ecules, one is monodentate to one Sr(II) cation, whereas the other bridges two Sr(II) cations. The ?(5)-bridging mode of the dianon and the ?(2)-bridging mode of the water mol-ecule generate a polymeric three-dimensional network which is consolidated by O-H?O hydrogen bonds. The Sr(II) cation exists in an undefined eight-coordinate environment.

SUBMITTER: Gao S 

PROVIDER: S-EPMC3238698 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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Poly[μ(2)-aqua-aqua-μ(5)-naphthalene-2,7-disulfonato-strontium].

Gao Shan S   Ng Seik Weng SW  

Acta crystallographica. Section E, Structure reports online 20111119 Pt 12


In the crystal structure of the polymeric title compound, [Sr(C(10)H(6)O(6)S(2))(H(2)O)(2)](n), the naphthalene-2,7-disulfonate dianion uses one -SO(3) unit to bind to two Sr(II) cations and the other -SO(3) unit to bind to three Sr(II) cations; of the two coordinated water mol-ecules, one is monodentate to one Sr(II) cation, whereas the other bridges two Sr(II) cations. The μ(5)-bridging mode of the dianon and the μ(2)-bridging mode of the water mol-ecule generate a polymeric three-dimensional  ...[more]

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