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Poly[?-aqua-?(4)-terephthalato-strontium].


ABSTRACT: In the title compound, [Sr(C(8)H(4)O(4))(H(2)O)](n), the Sr(II) atom exhibits coordination number eight, with six O atoms from four carboxylate groups (two bidentate and two monodentate) of terephthalate ligands and two water O atoms. The SrO(8) polyhedra are linked into inorganic chains by sharing three coplanar O atoms. These inorganic chains are extended along the b axis to form layers in the ab plane by O-C-O linking. Parallel layers are connected by terephthalic groups, forming a three-dimensional framework. O-H?O hydrogen-bonding inter-actions are observed.

SUBMITTER: Yang L 

PROVIDER: S-EPMC3051459 | biostudies-literature | 2011 Jan

REPOSITORIES: biostudies-literature

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Poly[μ-aqua-μ(4)-terephthalato-strontium].

Yang Lei L   Zhao Dan D   Li Guanghua G  

Acta crystallographica. Section E, Structure reports online 20110129 Pt 2


In the title compound, [Sr(C(8)H(4)O(4))(H(2)O)](n), the Sr(II) atom exhibits coordination number eight, with six O atoms from four carboxylate groups (two bidentate and two monodentate) of terephthalate ligands and two water O atoms. The SrO(8) polyhedra are linked into inorganic chains by sharing three coplanar O atoms. These inorganic chains are extended along the b axis to form layers in the ab plane by O-C-O linking. Parallel layers are connected by terephthalic groups, forming a three-dime  ...[more]

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