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Poly[[tetra-aqua-(?(3)-naphthalene-1,6-disulfonato-?O:O,O:O)strontium(II)] monohydrate].

ABSTRACT: In the crystal structure of the polymeric title compound, {[Sr(C(10)H(6)O(6)S(2))(H(2)O)(4)]·H(2)O}(n), the naphthalene-1,6-disulfonate dianion uses one -SO(3) unit to O,O'-chelate to an Sr(II) cation and its third O atom to bind to another Sr(II) cation. The other -SO(3) unit binds to yet another Sr(II) atom. The four coordinated water mol-ecules are monodentate but one is disordered over two positions in a 1:1 ratio. The ?(3)-bonding mode of the dianion generates a polymeric three-dimensional network; the network is consolidated by O-H?O hydrogen bonds. The Sr(II) cation exists in an undefined eight-coordinate environment.

SUBMITTER: Gao S

PROVIDER: S-EPMC3238671 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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Poly[[tetra-aqua-(μ(3)-naphthalene-1,6-disulfonato-κO:O,O:O)strontium(II)] monohydrate].

Gao Shan S Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20111116 Pt 12

In the crystal structure of the polymeric title compound, {[Sr(C(10)H(6)O(6)S(2))(H(2)O)(4)]·H(2)O}(n), the naphthalene-1,6-disulfonate dianion uses one -SO(3) unit to O,O'-chelate to an Sr(II) cation and its third O atom to bind to another Sr(II) cation. The other -SO(3) unit binds to yet another Sr(II) atom. The four coordinated water mol-ecules are monodentate but one is disordered over two positions in a 1:1 ratio. The μ(3)-bonding mode of the dianion generates a polymeric three-dimensional ...[more]

PMID: 22199562

Similar Datasets

Poly[?(2)-aqua-aqua-?(5)-naphthalene-2,7-disulfonato-strontium].

Project description:In the crystal structure of the polymeric title compound, [Sr(C(10)H(6)O(6)S(2))(H(2)O)(2)](n), the naphthalene-2,7-disulfonate dianion uses one -SO(3) unit to bind to two Sr(II) cations and the other -SO(3) unit to bind to three Sr(II) cations; of the two coordinated water mol-ecules, one is monodentate to one Sr(II) cation, whereas the other bridges two Sr(II) cations. The ?(5)-bridging mode of the dianon and the ?(2)-bridging mode of the water mol-ecule generate a polymeric three-dimensional network which is consolidated by O-H?O hydrogen bonds. The Sr(II) cation exists in an undefined eight-coordinate environment.

| S-EPMC3238698 | biostudies-literature

Poly[tetra-aqua-μ(3)-pyridine-3,5-dicarboxyl-ato-strontium(II)].

Project description:The reaction of strontium(II) nitrate with the proton-transfer compound (pdaH(2))(py-3,5-dc)·H(2)O (where pda = propane-1,3-diamine and py-3,5-dcH(2) = pyridine-3,5-dicarboxylic acid) leads to the formation of the title polymeric compound, [Sr(C(7)H(3)NO(4))(H(2)O)(4)](n). The propane-1,3-diaminium cation is not incorporated in this crystal structure. The Sr(II) atom lies on an inversion centre and is eight-coordinated by four O atoms from three py-3,5-dc ligands and four O atoms from four coordinated water mol-ecules. The coordination polyhedron of the Sr(II) atom is a distorted dodeca-hedron. These binuclear units are connected via the carboxyl-ate O atoms to build a one-dimensional polymeric chain. In the crystal structure, non-covalant inter-actions consisting of hydrogen bonds (X-H⋯O, with X = O and C) and π-π stacking inter-actions [3.4604 (19) Å] connect the various components to form a supra-molecular structure.

| S-EPMC2960463 | biostudies-literature

Poly[[aqua-(μ(5)-3,4,5,6-tetra-carb-oxy-cyclo-hexane-1,2-dicarboxyl-ato)strontium] monohydrate].

Project description:In the title compound, {[Sr(C(12)H(10)O(12))(H(2)O)]·H(2)O}(n), the Sr(II) ion is coordinated by six O atoms of five symmetry-related 3,4,5,6-tetra-carb-oxy-cyclo-hexane-1,2-dicarboxyl-ate ligands and one water mol-ecule in a slightly distorted monocapped trigonal-prismatic environment. The ligands bridge the Sr(II) ions, forming a two-dimensional structure. In the crystal, O-H⋯O hydrogen bonds further connect the structure into a three-dimensional network. The H atoms of two of the carboxyl groups were refined as half-occupancy.

| S-EPMC3238780 | biostudies-literature

Poly[di-?(3)-acetato-?(8)-(naphthalene-1,5-disulfonato)-dilead(II)].

Project description:In the polymeric title complex, [Pb(2)(CH(3)CO(2))(2)(C(10)H(6)O(6)S(2))](n), the acetate anion functions in a chelating mode and both O atoms also coordinate to adjacent Pb(II) atoms. The naphthalene-1,5-disulfonate dianion, which lies on a center of inversion, is connected to four Pb(II) atoms. The bridging modes of the monoanion and dianion give rise to a three-dimensional coordination polymer. The Pb(II) atom is eight-coordinate in the form of an undefined coordination polyhedron.

| S-EPMC3344422 | biostudies-literature

Poly[penta-?-aqua-?(6)-methyl-ene-disulfonato-?(5)-methyl-enedisulfonato-tetra-sodium(I)].

Project description:The title compound, [Na(4)(CH(2)O(6)S(2))(2)(H(2)O)(5)](n), was crystallized from an aqueous solution. The sodium ions are surrounded and bridged by O atoms from coordinated water mol-ecules and sulfonate ions in a three-dimensional neutral network. The crystal structure is also stabilized by an intricate system of hydrogen bonds.

| S-EPMC2961516 | biostudies-literature

catena-Poly[[[tetra-aqua-zinc(II)]-μ-4,4'-bipyridine-κN:N'] naphthalene-1,5-disulfonate].

Project description:In the title complex, {[Zn(C(10)H(8)N(2))(H(2)O)(4)](C(10)H(6)O(6)S(2))}(n), the [Zn(4,4'-bipy)(H(2)O)(4)](2+) (4,4'-bipy is 4,4'-bipyridine) cations are linked into linear chains along [001] by the 4,4'-bipy ligands. The Zn(II) ion exhibits a slightly distorted octa-hedral coordination geometry in which the four water mol-ecules are in the equatorial positions. The anions are hydrogen bonded to the polycationic chains by O-H⋯O hydrogen bonds, forming a three-dimensional network. The Zn(II) ion, 4,4'-bipy ligand and anion lie on special positions of 2/m site symmetry.

| S-EPMC2969998 | biostudies-literature

Tetra-aqua-diimidazole-nickel(II) naphthalene-1,5-disulfonate.

Project description:The triclinic unit cell of the title compound, [Ni(C(3)H(4)N(2))(2)(H(2)O)(4)](C(10)H(6)O(6)S(2)), contains one centrosymmetric cation and one centrosymmetric anion. In the cation, the Ni(II) ion is six-coordinated by two imidazole ligands [Ni-N = 2.0568 (14) Å] and four water mol-ecules [both independent Ni-O distances are 2.098 (1) Å] in a distorted octa-hedral geometry. Inter-molecular O-H⋯O and N-H⋯O hydrogen bonds form an extensive three-dimensional network, which consolidates the crystal packing.

| S-EPMC2960432 | biostudies-literature

Poly[[octa-aqua-tetra-kis-(?(3)-pyridine-2,5-dicarboxyl-ato)copper(II)diytterbium(III)] monohydrate].

Project description:The asymmetric unit of the title heterometallic polymeric coordination compound, {[CuYb(2)(C(7)H(3)NO(4))(4)(H(2)O)(8)]·H(2)O}(n), contains one Cu(II) cation located on an inversion center, a Yb(III) cation, two pyridine-2,5-dicarboxyl-ate (pda) anions, four coordination water mol-ecules a disordered lattice water molecule, which is half-occupied and is located close to an inversion center. The Cu(II) cation is N,O-chelated by two pda anions in the coordination basal plane and further coordinated by two carboxyl O atoms at the apical positions, with an elongated octa-hedral geometry. The Yb(III) atom is eight-coordinated in a distorted square-anti-prismatic geometry formed by two carboxyl-ate O atoms from two pda anions, and is N,O-chelated by one pda anion and four coordinated water mol-ecules. The pda anions bridge adjacent Yb and Cu cations, forming a three-dimensional polymeric structure. The crystal structure features extensive O-H?O hydrogen bonds. ?-? stacking is observed between parallel pyridine rings, the centroid-centroid distance being 3.843?(4)?Å.

| S-EPMC3089069 | biostudies-literature

Aqua-(4,5-dihydroxy-benzene-1,3-disulfonato-κO)bis-(1,10-phenanthroline-κN,N')cadmium(II) monohydrate.

Project description:In the title compound, [Cd(C(6)H(4)O(8)S(2))(C(12)H(8)N(2))(2)(H(2)O)]·H(2)O, each Cd(II) ion is coordinated by four N atoms [Cd-N = 2.310 (7)-2.341 (7) Å] from two 1,10-phenanthroline ligands, one O atom [Cd-O = 2.300 (6) Å] from a 4,5-dihydroxy-benzene-1,3-disulfonate ligand and one aqua O atom [Cd-O = 2.288 (7) Å] in a distorted octa-hedral geometry. The crystal packing exhibits inter-molecular O-H⋯O and C-H⋯O hydrogen bonds and π-π inter-actions evidenced by relatively short distances [3.525 (5)-3.937 (6) Å] between the centroids of the six-membered rings of neighbouring mol-ecules.

| S-EPMC2960182 | biostudies-literature

Poly[[[tetra-aqua-cobalt(II)]-μ-bipyridine] terephthalate].

Project description:The Co(II) atom in the title complex, {[Co(C(10)H(8)N(2))(H(2)O)(4)](C(8)H(4)O(4))}(n), is coordinated by two N atoms of two bipyridine ligands and four O atoms of four water mol-ecules in an octahedral geometry. The one-dimensional [Co(C(10)H(8)N(2))(H(2)O)(4)](2+) cation chain is further extended into a supra-molecular network via O-H⋯O hydrogen-bond inter-actions. The Co atom lies on a twofold rotation axis; another twofold rotation axis passes through the carboxylate carbon atoms and the attached ring C atoms.

| S-EPMC2915057 | biostudies-literature

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