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Poly[di-?(3)-acetato-?(8)-(naphthalene-1,5-disulfonato)-dilead(II)].

ABSTRACT: In the polymeric title complex, [Pb(2)(CH(3)CO(2))(2)(C(10)H(6)O(6)S(2))](n), the acetate anion functions in a chelating mode and both O atoms also coordinate to adjacent Pb(II) atoms. The naphthalene-1,5-disulfonate dianion, which lies on a center of inversion, is connected to four Pb(II) atoms. The bridging modes of the monoanion and dianion give rise to a three-dimensional coordination polymer. The Pb(II) atom is eight-coordinate in the form of an undefined coordination polyhedron.

SUBMITTER: Gao S

PROVIDER: S-EPMC3344422 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

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Poly[di-μ(3)-acetato-μ(8)-(naphthalene-1,5-disulfonato)-dilead(II)].

Gao Shan S Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20120428 Pt 5

In the polymeric title complex, [Pb(2)(CH(3)CO(2))(2)(C(10)H(6)O(6)S(2))](n), the acetate anion functions in a chelating mode and both O atoms also coordinate to adjacent Pb(II) atoms. The naphthalene-1,5-disulfonate dianion, which lies on a center of inversion, is connected to four Pb(II) atoms. The bridging modes of the monoanion and dianion give rise to a three-dimensional coordination polymer. The Pb(II) atom is eight-coordinate in the form of an undefined coordination polyhedron. ...[more]

PMID: 22590184

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