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Bis{1,2-bis-[bis-(3-meth-oxy-prop-yl)phosphan-yl]ethane-?P,P'}dichlorido-osmium(II).

ABSTRACT: In the centrosymmetric title compound, [OsCl(2)(C(18)H(40)O(4)P(2))(2)], the Os(II) atom adopts a trans-OsCl(2)P(4) geometry, arising from its coordination by two chelating diphosphane ligands and two chloride ions. One of the meth-oxy side chains of the ligand is disordered over two orientations in a 0.700?(6):0.300?(6) ratio.

SUBMITTER: Szymczak NK

PROVIDER: S-EPMC3238713 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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Bis{1,2-bis-[bis-(3-meth-oxy-prop-yl)phosphan-yl]ethane-κP,P'}dichlorido-osmium(II).

Szymczak Nathaniel K NK Zakharov Lev N LN Tyler David R DR

Acta crystallographica. Section E, Structure reports online 20111123 Pt 12

In the centrosymmetric title compound, [OsCl(2)(C(18)H(40)O(4)P(2))(2)], the Os(II) atom adopts a trans-OsCl(2)P(4) geometry, arising from its coordination by two chelating diphosphane ligands and two chloride ions. One of the meth-oxy side chains of the ligand is disordered over two orientations in a 0.700 (6):0.300 (6) ratio. ...[more]

PMID: 22199590

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