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Bis(μ-diethyl-phosphido-κP:P)bis-[bis(2,4,6-trimethyl-phen-yl)indium(III)].

ABSTRACT: The title compound, [In(2)(C(9)H(11))(4)(C(4)H(10)P)(2)], contains a centrosymmetric In(2)P(2) core with short inter-molecular In-P bonds. This core has acute P-In-P and obtuse In-P-In bond angles compared with other [R(2)InPR'(2)](2) analogues, due to the presence of the bulky aromatic substituents on the In atom and the non-sterically demanding ethyl substituents on the P atom.

SUBMITTER: Briand GG

PROVIDER: S-EPMC3246993 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Bis(2,4,6-trimethyl-phen-yl)zinc(II).

Project description:The title compound, [Zn(C(9)H(11))(2)] or Mes(2)Zn (Mes = mesityl = 2,4,6-trimethyl-phen-yl), crystallizes with a quarter of a mol-ecule in the asymmetric unit. The Zn(II) atom is in a strictly linear environment with a Zn-C bond length of 1.951?(5)?Å. Due to the imposed 2/m symmetry, both aromatic rings are coplanar. One of the methyl groups is disordered over two equally occupied positions.

| S-EPMC2969329 | biostudies-literature

trans-Dichloridobis[dicyclo-hex-yl(2,4,6-trimethyl-phen-yl)phosphane-κP]palladium(II).

Project description:The title compound, [PdCl(2)(C(21)H(33)P)(2)], forms a monomeric complex with a trans-square-planar coordination geometry about the Pd(II) atom which lies on an inversion centre. The Pd-P bond lengths are 2.3760 (13) Å, while the Pd-Cl bond lengths are 2.3172 (14) Å. The observed structure was found to be closely related to that of trans-dichloridobis[dicyclo-hex-yl(phen-yl)phosphane-κP]palladium(II), [PdCl(2){P(C(6)H(11))(2)(C(6)H(5))}(2)] [Burgoyne et al. (2012 ▶). Acta Cryst. E68, m404].

| S-EPMC3515096 | biostudies-literature

?-Carbonato-bis-(bis-{2-[(diethyl-amino)-meth-yl]phen-yl}bis-muth(III)).

Project description:The mol-ecular structure of the title compound, [Bi(2)(C(11)H(16)N)(4)(CO(3))], consists of a symmetrically bridging carbonato group which binds two [2-Et(2)NCH(2)C(6)H(4)](2)Bi units that are crystallographically related via a twofold rotation axis bis-ecting the carbonate group. The two Bi atoms and two of the C atoms directly bonded to bis-muth are quasi-planar [deviations of 0.323?(1) and 0.330?(9)Å for the Bi and C atoms, respectively] with the carbonate group. The remaining two ligands are in a trans arrangement relative to the quasi-planar (CBi)(2)CO(3) system. The metal atom is strongly coordinated by the N atom of one pendant arm [Bi-N = 2.739?(6)?Å], almost trans to the O atom, while the N atom of the other pendant arm exhibits a weaker intra-molecular inter-action [Bi?N = 3.659?(7)?Å] almost trans to a C atom. If both these intra-molecular N?Bi inter-actions per metal atom are considered, the overall coordination geometry at bis-muth becomes distorted square-pyramidal [(C,N)(2)BiO cores] and the compound can be described as a hypervalent 12-Bi-5 species. Additional quite short intra-molecular Bi?O inter-actions are also present [3.796?(8)-4.020?(9)?Å]. Inter-molecular associations through weak ?(6)?Bi inter-actions [Bi?centroid of benzene ring = 3.659?(1)?Å] lead to a ribbon-like supra-molecular association.

| S-EPMC3051654 | biostudies-literature

N-(2,4,6-Trimethyl-phen-yl)formamide.

Project description:The title compound, C(10)H(13)NO, was obtained as the unexpected, almost exclusive, product in the attempted synthesis of a manganese(I)-N-heterocyclic carbene (NHC) complex. The dihedral angle between the planes of the formamide moiety and the aryl ring is 68.06?(10)°. In the crystal, mol-ecules are linked by N-H?O hydrogen bonds, forming infinite chains along the c axis.

| S-EPMC3050174 | biostudies-literature

[2,7-Dimeth-oxy-8-(2,4,6-trimethyl-benzo-yl)naphthalen-1-yl](2,4,6-trimethyl-phen-yl)methanone.

Project description:In the title compound, C(32)H(32)O(4), the dihedral angle between the two benzene rings of the 2,4,6-trimethyl-benzoyl groups is 71.43?(7)°. The dihedral angles between the two benzene rings and the naphthalene ring system are 81.58?(5) and 84.92?(6)°. An intra-molecular C-H?O inter-action is observed.

| S-EPMC3254363 | biostudies-literature

N-(2,4,6-Trimethyl-phen-yl)maleamic acid.

Project description:The mol-ecular structure of the title compound, C(13)H(15)NO(3), is stabilized by a short intra-molecular O-H?O hydrogen bond within the maleamic unit. In the crystal, inter-molecular N-H?O hydrogen bonds link mol-ecules into zigzag chains propagating in [010].

| S-EPMC2971101 | biostudies-literature

N-(2,4,6-Trimethyl-phen-yl)succinamic acid.

Project description:The amide bond in the title compound {systematic name: 3-[(2,4,6-trimethyl-phen-yl)amino-carbon-yl]propionic acid}, C(13)H(17)NO(3), has a trans conformation. In the crystal, two mol-ecules form a centrosymmetric dimer connected by pairs of O-H?O hydrogen bonds. Inter-molecular N-H?O hydrogen bonds link the dimers into a three dimensional network.

| S-EPMC2977192 | biostudies-literature

2-(2,4,6-Trimethyl-phen-yl)-1,10-phenanthroline.

Project description:In the title mol-ecule, C(21)H(18)N(2), the mean plane of the benzene ring of the mesityl group forms a dihedral angle of 82.69 (4)° with that of the phenanthroline ring system. The crystal structure is stabilized by π-π stacking inter-actions between the phenanthroline system and the benzene ring of the mesityl group of a symmetry-related mol-ecule, with centroid-centroid distances of 3.7776 (14) and 3.7155 (13) Å.

| S-EPMC2968955 | biostudies-literature

Bis{2-[(2,4,6-trimethyl-phen-yl)imino-methyl]pyrrol-1-ido}palladium(II).

Project description:The title compound, [Pd(C(14)H(15)N(2))(2)], is a square-planar palladium complex composed of two deprotonated pyrrole-2-carbaldimine ligands coordinating a central Pd(II) atom. In the crystal, three crystallographically independent complex mol-ecules are observed, one of which is located in a general position, whereas the Pd(II) atoms of the other mol-ecules are situated on crystallographic inversion centers. The aromatic substituents at the imine N atoms in the three mol-ecules show dihedral angles of 87.6?(7)/83.64?(7), 74.3?(7) and 88.3?(7)° with respect to the corresponding PdN(4) plane.

| S-EPMC3569194 | biostudies-literature

1,3-Bis(2,4,6-trimethyl-phen-yl)-3H-imidazol-1-ium tetra-oxidorhenate(VII).

Project description:The title compound, (C(21)H(25)N(2))[ReO(4)], was formed as the unexpected product in an attempted synthesis of a rhenium(I)-N-heterocyclic carbene (NHC) complex. The compound has crystallographic mirror symmetry with both the cation and the tetrahedral anion located across a mirror plane. The cation and anion are linked by a C-H?O hydrogen bond.

| S-EPMC3238778 | biostudies-literature

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