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Poly[(2,2'-bipyridine-?N,N')(?(3)-2,4,6-trimethyl-isophthalato-?O,O:O:O,O)cadmium].

ABSTRACT: In the crystal structure of the polymeric title complex, [Cd(C(11)H(10)O(4))(C(10)H(8)N(2))](n), the Cd(II) cation is chelated by one 2,2-bipyridine ligand and two carboxyl groups from two trimethyl-isophthalate (TMIPA) anions, and is further coordinated by one carboxyl-ate O atom from a third TMIPA anion, forming a distorted penta-gonal-bipyramidal geometry. Each TMIPA anion bridges three Cd(II) cations, forming polymeric complex sheets parallel to (001). Weak C-H?O hydrogen bonding occurs between adjacent sheets.

SUBMITTER: Hou SG

PROVIDER: S-EPMC3254344 | biostudies-literature | 2012 Jan

REPOSITORIES: biostudies-literature

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Poly[(2,2'-bipyridine-κN,N')(μ(3)-2,4,6-trimethyl-isophthalato-κO,O:O:O,O)cadmium].

Hou Shao-Gang SG Jin Mei-Fang MF

Acta crystallographica. Section E, Structure reports online 20111223 Pt 1

In the crystal structure of the polymeric title complex, [Cd(C(11)H(10)O(4))(C(10)H(8)N(2))](n), the Cd(II) cation is chelated by one 2,2-bipyridine ligand and two carboxyl groups from two trimethyl-isophthalate (TMIPA) anions, and is further coordinated by one carboxyl-ate O atom from a third TMIPA anion, forming a distorted penta-gonal-bipyramidal geometry. Each TMIPA anion bridges three Cd(II) cations, forming polymeric complex sheets parallel to (001). Weak C-H⋯O hydrogen bonding occurs betw ...[more]

PMID: 22259378

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