Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Bis(?-propan-2-olato-?O:O)bis-[chlor-ido(propan-2-ol-?O)bis-(pro-pan-1-ol-ato-?O)tin(IV)].

ABSTRACT: The binuclear centrosymmetric title compound, [Sn(2)(C(3)H(7)O)(6)Cl(2)(C(3)H(8)O)(2)], exhibits an edge-shared double octahedral exhibits an edge-shared octa-hedral structure, which is distorted owing to the presence of asymmetric intra-molecular hydrogen bonds between the axially coordinated isopropanol and isopropoxide ligands. The H atom of the hy-droxy group is located nearer to an isoprop-oxy group with the longest Sn-O bond [2.1789?(17)?Å].

SUBMITTER: Klishin N

PROVIDER: S-EPMC3297279 | biostudies-literature | 2012 Mar

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Bis(μ-propan-2-olato-κO:O)bis-[chlor-ido(propan-2-ol-κO)bis-(pro-pan-1-ol-ato-κO)tin(IV)].

Klishin Nikolai N Brusylovets Oleksii O Brusilovets Anatoliy A Rusanov Eduard E

Acta crystallographica. Section E, Structure reports online 20120224 Pt 3

The binuclear centrosymmetric title compound, [Sn(2)(C(3)H(7)O)(6)Cl(2)(C(3)H(8)O)(2)], exhibits an edge-shared double octahedral exhibits an edge-shared octa-hedral structure, which is distorted owing to the presence of asymmetric intra-molecular hydrogen bonds between the axially coordinated isopropanol and isopropoxide ligands. The H atom of the hy-droxy group is located nearer to an isoprop-oxy group with the longest Sn-O bond [2.1789 (17) Å]. ...[more]

PMID: 22412469

Similar Datasets

Dimethyl-bis-(2-methyl-quinolin-8-olato-?(2) N,O)tin(IV).

Project description:The Sn(IV) cation in the title compound, [Sn(CH3)2(C10H8NO)2], is N,O-chelated by two 2-methyl-quinolin-8-olate anions and coordinated by two methyl groups in a skew-trapezoidal bipyramidal geometry. In the mol-ecule, the two quinoline ring systems are twisted to one another at 10.91?(18)°. The dimethyl-tin skeleton [C-Sn-C = 149.6?(2)°] is bent over the longer edge of the trapezoid that is defined by the four chelating atoms. Weak inter-molecular C-H?O hydrogen bonding occurs in the crystal.

| S-EPMC3588791 | biostudies-literature

Bis(4,6-dimethyl-pyrimidine-2-thiol-ato)dimethyl-tin(IV).

Project description:The asymmetric unit of the title complex, [Sn(CH(3))(2)(C(6)H(7)N(2)S)(2)], contains two independent mol-ecules with similar configurations. In each, the Sn(IV) cation is coordinated by two methyl and two 4,6-dimethyl-pyrimidine-2-thiol-ate anions in a distorted SnS(2)C(2) tetra-hedral geometry. In the two mol-ecules, the S-Sn-S bond angles are 87.70 (5) and 88.93 (4)°, while the C-Sn-C bond angles are 125.7 (3) and 125.9 (2)°. Weak C-H⋯N hydrogen bonding is present in the crystal structure.

| S-EPMC3007831 | biostudies-literature

Bis(5-chloro-quinolin-8-olato-?N,O)bis-(propan-2-olato-?O)titanium(IV).

Project description:The Ti(IV) atom in the title compound, [Ti(C(9)H(5)ClNO)(2)(C(3)H(7)O)(2)], is chelated by the substituted quinolin-8-olate anions in a distorted octa-hedral geometry. The N-donor atoms are in a cis alignment as are the O atoms of the propan-2-olate groups; the O atoms of the quinolin-8-olate groups are trans to each other. One C atom of one propan-2-olate group is disordered over two positions with occupancies of 0.733?(8):0.267?(8).

| S-EPMC2968443 | biostudies-other

Bis(μ-quinolin-8-olato)-κN,O:O;κO:N,O-bis-[chloridomethyl-phenyl-tin(IV)].

Project description:The Sn(IV) atom in the centrosymmetric dinculear title compound, [Sn(2)(CH(3))(2)(C(6)H(5))(2)(C(9)H(6)NO)(2)Cl(2)], shows a trans-C(2)SnNO(2)Cl distorted octa-hedral coordination [C-Sn-C = 157.83 (8)°]. The quinolin-8-olate anion chelates to the Sn atom; its O atom also binds to the inversion-related Sn atom, forming the dinuclear compound. In the crystal structure, weak inter-molecular C-H⋯Cl hydrogen bonding links the mol-ecules, forming supra-molecular chains running along [100].

| S-EPMC3007587 | biostudies-literature

(μ-2,3-Dihydroxy-butane-1,4-dithiol-ato)bis-[triphenyl-tin(IV)].

Project description:In the title compound, [Sn(2)(C(6)H(5))(6)(C(4)H(8)O(2)S(2))], the geometry around the Sn atoms is distorted tetra-hedral. The hydr-oxy groups are involved in O-H⋯O hydrogen bonding, which connects mol-ecules into centrosymmetric dimers.

| S-EPMC2979966 | biostudies-literature

Benzyl-chloridobis(quinolin-8-olato)tin(IV).

Project description:In the title compound, [Sn(C(7)H(7))(C(9)H(6)NO)(2)Cl], the Sn(IV) ion is in a distorted octa-hedral coordination environment formed by the O and N atoms of two bis-chelating quinolin-8-olate ligands, a Cl atom and a C atom from a benzyl ligand. The axial sites are occupied by an N atom of a quinolinate ligand and the C atom of the benzyl ligand. The axial Sn-N bond is slightly shorter than the equatorial Sn-N bond.

| S-EPMC2977110 | biostudies-literature

Dimethyl-bis-(pyrazine-2-carboxyl-ato-?(2)N(1),O)tin(IV).

Project description:In the title compound, [Sn(CH(3))(2)(C(5)H(3)N(2)O(2))(2)], the Sn(IV) atom is twice N,O-chelated by two pyrazine-2-carboxyl-ate ligands. The distorted six-coordination is completed by two tin-bound methyl C atoms. The C(2)N(2)O(2) donor set defines a skewed trapezoidal-bipyramidal geometry. Inter-molecular ?-? inter-actions between the pyrazine rings [centroid-centroid distance = 3.8112?(13)?Å] are observed.

| S-EPMC3515132 | biostudies-literature

Dimethyl-bis(3-methylsulfanyl-1,2,4-thia-diazole-5-thiol-ato)tin(IV).

Project description:In the title compound, [Sn(CH(3))(2)(C(3)H(3)N(2)S(3))(2)], the Sn(IV) atom is coordinated within a C(2)N(2)S(2) donor set that defines a skew-trapezoidal bipyramidal geometry in which the methyl groups lie over the weakly coordinated N atoms. Two independent mol-ecules comprise the asymmetric unit, each of which lies on a mirror plane that passes through the C(2)Sn unit.

| S-EPMC2970034 | biostudies-literature

Bis(n-do-decyl-ammonium) bis-(chlor-anil-ato)di-ethano-lcuprate(II).

Project description:In the title compound, (C12H25NH3)2[Cu(C6Cl2O4)2(C2H5OH)2], the Cu(II) atom lies on a crystallographic inversion center and is coordinated in a distorted octa-hedral geometry by four O atoms of two chloranilate ligands and two O atoms of two ethanol mol-ecules which are trans to each other in the axial positions. In the crystal, the Cu(II) mononuclear dianions are linked by O-H⋯O hydrogen bonds into a tape along the a-axis direction. The tapes are linked through N-H⋯O hydrogen bonds between the dianion and the n-do-decyl-ammonium cation, forming a two-dimensional network parallel to the ab plane.

| S-EPMC3998266 | biostudies-literature

Di-?(2)-chlorido-dichloridoocta-methyldi-?(3)-oxido-tetra-tin(IV) bis[chloridodimeth-yl(pyrrolidine-1-carbodithio-ato-?(2)S,S')tin(IV)].

Project description:In the title co-crystal, [Sn(4)(CH(3))(8)Cl(4)O(2)]·2[Sn(CH(3))(2)Cl(C(4)H(8)NS(2))], all the Sn(IV) atoms are in distorted trigonal-bipyramidal environments. In the mononuclear species, the carbodithio-ate ligand is unsymmetrically coordinated to the Sn(IV) atom, with Sn-S distances of 2.6722?(12) and 2.4706?(11)?Å. All atoms with the exception of the methyl groups and one of the pyrrolidine ring CH(2) groups lie on a crystallographic mirror plane. The pyrrolidine ring exhibits an envelope conformation; the C atom at the flap is disordered above and below the plane of symmetry with fixed occupation factors of 0.50. The centrosymmetric dimer species consists of a central Sn(2)O(2) unit with two adjacent Sn(2)OCl four-membered rings.

| S-EPMC3344393 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data