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Bis(?-propan-2-olato-?O:O)bis-[chlor-ido(propan-2-ol-?O)bis-(pro-pan-1-ol-ato-?O)tin(IV)].

ABSTRACT: The binuclear centrosymmetric title compound, [Sn(2)(C(3)H(7)O)(6)Cl(2)(C(3)H(8)O)(2)], exhibits an edge-shared double octahedral exhibits an edge-shared octa-hedral structure, which is distorted owing to the presence of asymmetric intra-molecular hydrogen bonds between the axially coordinated isopropanol and isopropoxide ligands. The H atom of the hy-droxy group is located nearer to an isoprop-oxy group with the longest Sn-O bond [2.1789?(17)?Å].

SUBMITTER: Klishin N

PROVIDER: S-EPMC3297279 | biostudies-literature | 2012 Mar

REPOSITORIES: biostudies-literature

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Bis(μ-propan-2-olato-κO:O)bis-[chlor-ido(propan-2-ol-κO)bis-(pro-pan-1-ol-ato-κO)tin(IV)].

Klishin Nikolai N Brusylovets Oleksii O Brusilovets Anatoliy A Rusanov Eduard E

Acta crystallographica. Section E, Structure reports online 20120224 Pt 3

The binuclear centrosymmetric title compound, [Sn(2)(C(3)H(7)O)(6)Cl(2)(C(3)H(8)O)(2)], exhibits an edge-shared double octahedral exhibits an edge-shared octa-hedral structure, which is distorted owing to the presence of asymmetric intra-molecular hydrogen bonds between the axially coordinated isopropanol and isopropoxide ligands. The H atom of the hy-droxy group is located nearer to an isoprop-oxy group with the longest Sn-O bond [2.1789 (17) Å]. ...[more]

PMID: 22412469

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