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Chlorido[2-({[2-(diphenyl-phosphan-yl)-benzyl-idene]amino}-meth-yl)thio-phene-?N,P]methyl-palladium(II).

ABSTRACT: In the title compound, [Pd(CH(3))Cl(C(24)H(20)NPS)], the Pd(II) ion is coordinated in a distorted square-planar environment which includes the P and N atoms of the bis-chelating ligand. The thio-phene ring is rotationally ordered, unlike in the majority of crystal structures containing this group.

SUBMITTER: Motswainyana WM

PROVIDER: S-EPMC3297280 | biostudies-literature | 2012 Mar

REPOSITORIES: biostudies-literature

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Chlorido[2-({[2-(diphenyl-phosphan-yl)-benzyl-idene]amino}-meth-yl)thio-phene-κN,P]methyl-palladium(II).

Motswainyana William M WM Onani Martin O MO Lalancette Roger A RA

Acta crystallographica. Section E, Structure reports online 20120229 Pt 3

In the title compound, [Pd(CH(3))Cl(C(24)H(20)NPS)], the Pd(II) ion is coordinated in a distorted square-planar environment which includes the P and N atoms of the bis-chelating ligand. The thio-phene ring is rotationally ordered, unlike in the majority of crystal structures containing this group. ...[more]

PMID: 22412470

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