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Tetra-kis{1-[4-(1H-imidazol-1-yl-?N(3))phen-yl]ethanone}bis-(isothio-cyanato-?N)nickel(II).

ABSTRACT: The title complex mol-ecule, [Ni(NCS)(2)(C(11)H(10)N(2)O)(4)], has a crystallographically imposed centre of symmetry. The Ni(II) atom is coordinated by the N atoms of two trans-arranged NCS(-) anions and four 1-[4-(1H-imidazol-1-yl)phen-yl]ethan-one ligands in a distorted octa-hedral geometry. In the crystal, C-H?S hydrogen bonds link the complex mol-ecules into chains parallel to the b axis. The chains are further connected by C-H?O hydrogen bonds, forming layers parallel to the bc plane.

SUBMITTER: Zhao J

PROVIDER: S-EPMC3393218 | biostudies-literature | 2012 Jul

REPOSITORIES: biostudies-literature

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Tetra-kis{1-[4-(1H-imidazol-1-yl-κN(3))phen-yl]ethanone}bis-(isothio-cyanato-κN)nickel(II).

Zhao Juan J Liu Bao-Cheng BC

Acta crystallographica. Section E, Structure reports online 20120623 Pt 7

The title complex mol-ecule, [Ni(NCS)(2)(C(11)H(10)N(2)O)(4)], has a crystallographically imposed centre of symmetry. The Ni(II) atom is coordinated by the N atoms of two trans-arranged NCS(-) anions and four 1-[4-(1H-imidazol-1-yl)phen-yl]ethan-one ligands in a distorted octa-hedral geometry. In the crystal, C-H⋯S hydrogen bonds link the complex mol-ecules into chains parallel to the b axis. The chains are further connected by C-H⋯O hydrogen bonds, forming layers parallel to the bc plane. ...[more]

PMID: 22807786

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