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Bis(2-amino-3-methyl-pyridine-?N(1))dichloridomercury(II).

ABSTRACT: In the title compound, [HgCl(2)(C(6)H(8)N(2))(2)], the two independent Hg(II) cations are each located on a twofold rotation axis and coordinated by two pyridine N atoms from two 2-amino-3-methyl-pyridine ligands and two Cl(-) anions in a distorted tetra-hedral geometry. An intra-molecular N-H?Cl hydrogen bond occurs in each independent complex mol-ecule. Inter-molecular N-H?Cl hydrogen bonds occur in the crystal structure.

SUBMITTER: Tadjarodi A

PROVIDER: S-EPMC3414149 | biostudies-literature | 2012 Aug

REPOSITORIES: biostudies-literature

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Bis(2-amino-3-methyl-pyridine-κN(1))dichloridomercury(II).

Tadjarodi Azadeh A Bijanzad Keyvan K Notash Behrouz B

Acta crystallographica. Section E, Structure reports online 20120721 Pt 8

In the title compound, [HgCl(2)(C(6)H(8)N(2))(2)], the two independent Hg(II) cations are each located on a twofold rotation axis and coordinated by two pyridine N atoms from two 2-amino-3-methyl-pyridine ligands and two Cl(-) anions in a distorted tetra-hedral geometry. An intra-molecular N-H⋯Cl hydrogen bond occurs in each independent complex mol-ecule. Inter-molecular N-H⋯Cl hydrogen bonds occur in the crystal structure. ...[more]

PMID: 22904756

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Di-μ-chlorido-bis-[(2-amino-4-methyl-pyridine-κN)-chloridomercury(II)].

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Bis(3-methyl-pyridine-κN)bis-(thio-cyanato-κN)zinc.

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