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N-(2-Bromo-benz-yl)cinchoninium bromide.

ABSTRACT: The title compound {systematic name: 1-(2-bromo-benz-yl)-5-ethenyl-2-[hy-droxy(quinolin-4-yl)meth-yl]-1-aza-bicyclo-[2.2.2]octan-1-ium bromide}, C(26)H(28)BrN(2)O(+)·Br(-), is a chiral quater-nary ammonium salt of one of the Cinchona alkaloids. The planes of the quinoline and of the bromo-benzyl substituent are inclined to one another by 9.11 (9)°. A weak intra-molecular C-H⋯O hydrogen bond occurs. The crystal structure features strong O-H⋯Br hydrogen bonds and weak C-H⋯Br inter-actions.

SUBMITTER: Skorska-Stania A

PROVIDER: S-EPMC3435830 | biostudies-literature | 2012 Sep

REPOSITORIES: biostudies-literature

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N-(2-Bromo-benz-yl)cinchoninium bromide.

Skórska-Stania Agnieszka A Jezierska-Zięba Magdalena M Kąkol Barbara B Fedoryński Michał M Oleksyn Barbara J BJ

Acta crystallographica. Section E, Structure reports online 20120831 Pt 9

The title compound {systematic name: 1-(2-bromo-benz-yl)-5-ethenyl-2-[hy-droxy(quinolin-4-yl)meth-yl]-1-aza-bicyclo-[2.2.2]octan-1-ium bromide}, C(26)H(28)BrN(2)O(+)·Br(-), is a chiral quater-nary ammonium salt of one of the Cinchona alkaloids. The planes of the quinoline and of the bromo-benzyl substituent are inclined to one another by 9.11 (9)°. A weak intra-molecular C-H⋯O hydrogen bond occurs. The crystal structure features strong O-H⋯Br hydrogen bonds and weak C-H⋯Br inter-actions. ...[more]

PMID: 22969676

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