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(Acetato-?(2)O,O')(acetato-?O)bis(2-amino-3-methyl-pyridine-?N(1))cobalt(II).

ABSTRACT: In the title compound, [Co(CH(3)COO)(2)(C(6)H(8)N(2))(2)], the Co(II) ion is five-coordinated by two pyridine N atoms from two 2-amino-3-methyl-pyridine ligands, two O atoms from one acetate ion and one O atom from another acetate ion in a distorted trigonal-bipyramidal geometry. The pyridine rings are nearly perpendicular to each other [dihedral angle = 84.49?(16)°]. The crystal packing is stabilized by intra-molecular and inter-molecular N-H?O hydrogen-bonding inter-actions.

SUBMITTER: Tadjarodi A

PROVIDER: S-EPMC3470146 | biostudies-literature | 2012 Oct

REPOSITORIES: biostudies-literature

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(Acetato-κ(2)O,O')(acetato-κO)bis(2-amino-3-methyl-pyridine-κN(1))cobalt(II).

Tadjarodi Azadeh A Bijanzad Keyvan K Notash Behrouz B

Acta crystallographica. Section E, Structure reports online 20120915 Pt 10

In the title compound, [Co(CH(3)COO)(2)(C(6)H(8)N(2))(2)], the Co(II) ion is five-coordinated by two pyridine N atoms from two 2-amino-3-methyl-pyridine ligands, two O atoms from one acetate ion and one O atom from another acetate ion in a distorted trigonal-bipyramidal geometry. The pyridine rings are nearly perpendicular to each other [dihedral angle = 84.49 (16)°]. The crystal packing is stabilized by intra-molecular and inter-molecular N-H⋯O hydrogen-bonding inter-actions. ...[more]

PMID: 23125590

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