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4-Dimethyl-amino-N'-(4-nitro-benzyl-idene)benzohydrazide methanol monosolvate.

ABSTRACT: In the title compound, C(16)H(16)N(4)O(3)·CH(3)OH, the aromatic rings form a dihedral angle of 0.4?(2)°. The nitro group is twisted from the attached benzene ring by 7.5?(2)°. In the crystal, N-H?O and O-H?O hydrogen bonds link alternating hydrazone and methanol mol-ecules into chains in [100]. The crystal packing exhibits ?-? inter-actions between aromatic rings from neighbouring chains [centroid-centroid distances = 3.734?(3) and 3.903?(3)?Å].

SUBMITTER: Zhang X

PROVIDER: S-EPMC3470190 | biostudies-literature | 2012 Oct

REPOSITORIES: biostudies-literature

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4-Dimethyl-amino-N'-(4-nitro-benzyl-idene)benzohydrazide methanol monosolvate.

Zhang Xiyue X Fu Xiaobo X Tan Langzhu L Wang Chaixia C Fan Weixing W

Acta crystallographica. Section E, Structure reports online 20120901 Pt 10

In the title compound, C(16)H(16)N(4)O(3)·CH(3)OH, the aromatic rings form a dihedral angle of 0.4 (2)°. The nitro group is twisted from the attached benzene ring by 7.5 (2)°. In the crystal, N-H⋯O and O-H⋯O hydrogen bonds link alternating hydrazone and methanol mol-ecules into chains in [100]. The crystal packing exhibits π-π inter-actions between aromatic rings from neighbouring chains [centroid-centroid distances = 3.734 (3) and 3.903 (3) Å]. ...[more]

PMID: 23125634

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