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Sodium penta-fluoro-phenyl-borate.

ABSTRACT: The crystal structure of the title compound, Na[(C(6)F(5))BH(3)], is composed of discrete anions and cations. The sodium cations are surrounded by four anions with three short Na?B [2.848?(8), 2.842?(7) and 2.868?(8)?Å] and two short Na?F contacts [2.348?(5) and 2.392?(5)?Å], forming a three-dimensional network. The anion is the first structural example of a pentafluorophenyl ring carrying a BH(3) group.

SUBMITTER: Vitze H

PROVIDER: S-EPMC3515123 | biostudies-literature | 2012 Nov

REPOSITORIES: biostudies-literature

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Sodium penta-fluoro-phenyl-borate.

Vitze Hannes H Lerner Hans-Wolfram HW Bolte Michael M

Acta crystallographica. Section E, Structure reports online 20121020 Pt 11

The crystal structure of the title compound, Na[(C(6)F(5))BH(3)], is composed of discrete anions and cations. The sodium cations are surrounded by four anions with three short Na⋯B [2.848 (8), 2.842 (7) and 2.868 (8) Å] and two short Na⋯F contacts [2.348 (5) and 2.392 (5) Å], forming a three-dimensional network. The anion is the first structural example of a pentafluorophenyl ring carrying a BH(3) group. ...[more]

PMID: 23284350

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