Unknown

Dataset Information

0

Catena-Poly[[tri-phenyl-tin(IV)]-?-N-(4-acetyl-phen-yl)maleamato].

ABSTRACT: The crystal structure of the polymeric title compound, [Sn(C6H5)3(C12H10NO4)] n , comprises polymeric chains whereby adjacent Sn atoms are bridged by carboxyl-ate and amide carbonyl O atoms [Sn-O = 2.115?(15) and 2.653?(1)?Å, respectively]. The Sn(IV) atom is five-coordinated showing a distorted trigonal-bipyramid geometry, with the three phenyl ipso-C atoms defining the trigonal plane and the axial positions occupied by O atoms [O-Sn-O = 171.91?(5)°]. Intra-molecular N-H?O hydrogen bonding leads to a seven-membered loop. There is an intra-molecular C-H?O inter-action within the polymeric chain. An inter-molecular C-H?O inter-action along c links the polymeric chains into sheets which are linked into a three-dimensional network via C-H?? inter-actions.

SUBMITTER: Bhatti MH 

PROVIDER: S-EPMC3793673 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

catena-Poly[[tri-phenyl-tin(IV)]-μ-N-(4-acetyl-phen-yl)maleamato].

Bhatti Moazzam H MH   Yunus Uzma U   Mussarat Nosheen N   Helliwell Madeleine M   Prendergast Richard R  

Acta crystallographica. Section E, Structure reports online 20130703 Pt 8

The crystal structure of the polymeric title compound, [Sn(C6H5)3(C12H10NO4)] n , comprises polymeric chains whereby adjacent Sn atoms are bridged by carboxyl-ate and amide carbonyl O atoms [Sn-O = 2.115 (15) and 2.653 (1) Å, respectively]. The Sn(IV) atom is five-coordinated showing a distorted trigonal-bipyramid geometry, with the three phenyl ipso-C atoms defining the trigonal plane and the axial positions occupied by O atoms [O-Sn-O = 171.91 (5)°]. Intra-molecular N-H⋯O hydrogen bonding lead  ...[more]

Similar Datasets

Unknown catena-Poly[[trimethyl-tin(IV)]-μ-phenyl-seleninato-κO:O'].
| S-EPMC3051585 | biostudies-literature
Unknown Crystal structure of catena-poly[[tri-methyl-tin(IV)]-μ-2-(2-nitro-phen-yl)acetato-κ(2) O:O'].
| S-EPMC4350728 | biostudies-literature
Unknown catena-Poly[[trimethyl-tin(IV)]-μ-quinaldato].
| S-EPMC2914916 | biostudies-literature
Unknown catena-Poly[[trimethyl-tin(IV)]-μ-[(E)-2-methyl-3-(3-methyl-phen-yl)acrylato-κO:O']].
| S-EPMC2961908 | biostudies-literature
Unknown catena-Poly[[di-tert-butyl-tin(IV)]-μ-oxalato].
| S-EPMC3998617 | biostudies-literature
Unknown catena-Poly[[trimethyl-tin(IV)]-?-2-phenyl-butano-ato].
| S-EPMC3011523 | biostudies-literature
Unknown catena-Poly[[triphenyl-tin(IV)]-?-phenyl-phosphinato-?O:O'].
| S-EPMC3238605 | biostudies-literature
Unknown catena-Poly[[diphenyl-propyl-tin(IV)]-μ-chloroacetato-κO:O'].
| S-EPMC2961930 | biostudies-literature
Unknown catena-Poly[[triphenyl-tin(IV)]-μ(2)-[3-(cyclo-hexyl-carbamo-yl)propanoato-κO:O]].
| S-EPMC2983217 | biostudies-literature
Unknown catena-Poly[[tribenzyl-tin(IV)]-μ-2-(piperidin-1-ylcarbothio-ylsulfan-yl)acetato-κO:O'].
| S-EPMC2983362 | biostudies-literature