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Di-?-hydroxido-?(4) O:O-di-?-perchlorato-?(4) O:O'-bis-[(2,2'-bi-pyridine-?(2) N,N')copper(II)].

ABSTRACT: In the title binuclear copper(II) complex, [Cu2(ClO4)2(OH)2(C10H8N2)2], the Cu(II) ion is coordinated in the form of a Jahn-Teller distorted octahedron by two bi-pyridine N atoms, two perchlorate O atoms and two hydroxide O atoms, and displays a distorted octa-hedral geometry. The mol-ecule belongs to the symmetry point group C 2h . The Cu(II) ion is located on a twofold rotation axis and the hydroxide and perchlorate ligands are located on a mirror plane. Within the dinuclear mol-ecule, the Cu?Cu separation is 2.8614?(7)?Å. The crystal structure exhibits O-H?O, C-H?O and ?-? [centroid-centroid distance = 3.5374?(13)?Å] inter-actions.

SUBMITTER: Saravanan B

PROVIDER: S-EPMC3884256 | biostudies-literature | 2013 Oct

REPOSITORIES: biostudies-literature

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Di-μ-hydroxido-κ(4) O:O-di-μ-perchlorato-κ(4) O:O'-bis-[(2,2'-bi-pyridine-κ(2) N,N')copper(II)].

Saravanan B B Jayamani A A Sengottuvelan N N Chakkaravarthi G G Manivannan V V

Acta crystallographica. Section E, Structure reports online 20131016 Pt 11

In the title binuclear copper(II) complex, [Cu2(ClO4)2(OH)2(C10H8N2)2], the Cu(II) ion is coordinated in the form of a Jahn-Teller distorted octahedron by two bi-pyridine N atoms, two perchlorate O atoms and two hydroxide O atoms, and displays a distorted octa-hedral geometry. The mol-ecule belongs to the symmetry point group C 2h . The Cu(II) ion is located on a twofold rotation axis and the hydroxide and perchlorate ligands are located on a mirror plane. Within the dinuclear mol-ecule, the Cu⋯ ...[more]

PMID: 24454032

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