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Bis(1-benzyl-1H-benzimidazole-?N (3))di-chlorido-zinc.

ABSTRACT: In the title compound, [ZnCl2(C14H12N2)2], the Zn(II) atom exhibits a distorted tetra-hedral coordination geometry involving two chloride anions and two N-atom donors from 1-benzyl-1H-benzimidazole ligands. In both ligands, the benzyl and benzimidazole rings are nearly perpendicular [dihedral angles = 81.7?(2) and 81.5?(2)°]. The two benzimidazole systems are essentially planar [maximum deviations = 0.015?(3) and 0.020?(2)?Å] and form a dihedral angle of 78.09?(8)°. In the crystal, centrosymmetrically related mol-ecules are linked by pairs of C-H?Cl hydrogen bonds into chains parallel to the a axis.

SUBMITTER: Bouhfid R

PROVIDER: S-EPMC3998485 | biostudies-literature | 2014 Mar

REPOSITORIES: biostudies-literature

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Bis(1-benzyl-1H-benzimidazole-κN (3))di-chlorido-zinc.

Bouhfid Rachid R Essassi El Mokhtar el M Saadi Mohamed M El Ammari Lahcen L

Acta crystallographica. Section E, Structure reports online 20140212 Pt 3

In the title compound, [ZnCl2(C14H12N2)2], the Zn(II) atom exhibits a distorted tetra-hedral coordination geometry involving two chloride anions and two N-atom donors from 1-benzyl-1H-benzimidazole ligands. In both ligands, the benzyl and benzimidazole rings are nearly perpendicular [dihedral angles = 81.7 (2) and 81.5 (2)°]. The two benzimidazole systems are essentially planar [maximum deviations = 0.015 (3) and 0.020 (2) Å] and form a dihedral angle of 78.09 (8)°. In the crystal, centrosymmetr ...[more]

PMID: 24764954

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