Unknown

Dataset Information

0

Bis(1-benzyl-1H-benzimidazole-?N (3))di-chlorido-zinc.


ABSTRACT: In the title compound, [ZnCl2(C14H12N2)2], the Zn(II) atom exhibits a distorted tetra-hedral coordination geometry involving two chloride anions and two N-atom donors from 1-benzyl-1H-benzimidazole ligands. In both ligands, the benzyl and benzimidazole rings are nearly perpendicular [dihedral angles = 81.7?(2) and 81.5?(2)°]. The two benzimidazole systems are essentially planar [maximum deviations = 0.015?(3) and 0.020?(2)?Å] and form a dihedral angle of 78.09?(8)°. In the crystal, centrosymmetrically related mol-ecules are linked by pairs of C-H?Cl hydrogen bonds into chains parallel to the a axis.

SUBMITTER: Bouhfid R 

PROVIDER: S-EPMC3998485 | biostudies-literature | 2014 Mar

REPOSITORIES: biostudies-literature

altmetric image

Publications

Bis(1-benzyl-1H-benzimidazole-κN (3))di-chlorido-zinc.

Bouhfid Rachid R   Essassi El Mokhtar el M   Saadi Mohamed M   El Ammari Lahcen L  

Acta crystallographica. Section E, Structure reports online 20140212 Pt 3


In the title compound, [ZnCl2(C14H12N2)2], the Zn(II) atom exhibits a distorted tetra-hedral coordination geometry involving two chloride anions and two N-atom donors from 1-benzyl-1H-benzimidazole ligands. In both ligands, the benzyl and benzimidazole rings are nearly perpendicular [dihedral angles = 81.7 (2) and 81.5 (2)°]. The two benzimidazole systems are essentially planar [maximum deviations = 0.015 (3) and 0.020 (2) Å] and form a dihedral angle of 78.09 (8)°. In the crystal, centrosymmetr  ...[more]

Similar Datasets

| S-EPMC2977612 | biostudies-literature
| S-EPMC2915116 | biostudies-literature
| S-EPMC3884270 | biostudies-literature
| S-EPMC4011251 | biostudies-literature
| S-EPMC3008101 | biostudies-literature
| S-EPMC2969313 | biostudies-literature
| S-EPMC2961044 | biostudies-literature
| S-EPMC3238745 | biostudies-literature
| S-EPMC3011569 | biostudies-literature
| S-EPMC3051965 | biostudies-literature