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Bis[?-N-(pyridin-2-yl)methane-sulfon-amido-?(2) N:N']silver(I).

ABSTRACT: In the title compound, [Ag2(C6H7N2O2S)2], the Ag(I) atom is coordinated by two N atoms from two N-(pyridin-2-yl)methane-sulfonamidate anions in a slightly bent linear geometry [N-Ag-N = 166.03?(7)°]. The Ag(I) atoms are bridged by the N-(pyridin-2-yl)methane-sulfonamidate anions, forming a centrosymmetric dinuclear mol-ecule, in which the Ag?Ag distance is 2.7072?(4)?Å.

SUBMITTER: Hu HL

PROVIDER: S-EPMC4004429 | biostudies-literature | 2013 Dec

REPOSITORIES: biostudies-literature

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Bis[μ-N-(pyridin-2-yl)methane-sulfon-amido-κ(2) N:N']silver(I).

Hu Hui-Ling HL Yeh Chun-Wei CW

Acta crystallographica. Section E, Structure reports online 20131127 Pt 12

In the title compound, [Ag2(C6H7N2O2S)2], the Ag(I) atom is coordinated by two N atoms from two N-(pyridin-2-yl)methane-sulfonamidate anions in a slightly bent linear geometry [N-Ag-N = 166.03 (7)°]. The Ag(I) atoms are bridged by the N-(pyridin-2-yl)methane-sulfonamidate anions, forming a centrosymmetric dinuclear mol-ecule, in which the Ag⋯Ag distance is 2.7072 (4) Å. ...[more]

PMID: 24860285

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