Unknown

Dataset Information

0

Crystal structure of tris-[?2-bis-(di-phenyl-phosphan-yl)methane-?(2) P:P']di-?3-bromido-tris-ilver(I) bromide-N,N'-phenyl-thio-urea (1/1).

ABSTRACT: The title complex, [Ag3Br2(C25H22P2)3]Br·C7H8N2S, comprises a trinuclear [Ag3Br2(C25H22P2)3](+) unit, a Br(-) anion and one N,N'-di-methyl-thio-urea mol-ecule (ptu). Three Ag(I) ions are linked via two ?3-bridging Br atoms, leading to a distorted triangular bipyramid with an Ag?Ag separation range of 3.1046?(6)-3.3556?(6)?Å. The triangular Ag3 arrangement is stabilized by six P atoms from three chelating bis-(di-phenyl-phosphan-yl)methane (dppm) ligands. The Ag(I) ion presents a distorted tetra-hedral coordination geometry. In the crystal, the bromide anion is connected to the ptu mol-ecule through N-H?Br hydrogen bonds [graph-set motif R 2 (1)(6)]. Each bromide/ptu aggregate links the complex ion via C-H?S and C-H?Br hydrogen bonds, leading to the formation of a three-dimensional network. Two phenyl rings from two dppm ligands were modelled as disordered over two sites.

SUBMITTER: Nimthong-Roldan A 

PROVIDER: S-EPMC4438794 | biostudies-literature | 2015 Apr

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Crystal structure of tris-[μ2-bis-(di-phenyl-phosphan-yl)methane-κ(2) P:P']di-μ3-bromido-tris-ilver(I) bromide-N,N'-phenyl-thio-urea (1/1).

Nimthong-Roldán Arunpatcha A   Wattanakanjana Yupa Y   Rodkeaw Jintana J  

Acta crystallographica. Section E, Crystallographic communications 20150321 Pt 4

The title complex, [Ag3Br2(C25H22P2)3]Br·C7H8N2S, comprises a trinuclear [Ag3Br2(C25H22P2)3](+) unit, a Br(-) anion and one N,N'-di-methyl-thio-urea mol-ecule (ptu). Three Ag(I) ions are linked via two μ3-bridging Br atoms, leading to a distorted triangular bipyramid with an Ag⋯Ag separation range of 3.1046 (6)-3.3556 (6) Å. The triangular Ag3 arrangement is stabilized by six P atoms from three chelating bis-(di-phenyl-phosphan-yl)methane (dppm) ligands. The Ag(I) ion presents a distorted tetra-  ...[more]

Similar Datasets

Unknown Crystal structure of tris-[?2-bis-(di-phenyl-phosphan-yl)methane-?(2) P:P']di-?3-iodido-tris-ilver(I) iodide-N-phenyl-thio-urea (1/1).
| S-EPMC4645055 | biostudies-literature
Unknown Tris(allyl-thio-urea-?S)bromidozinc(II) bromide.
| S-EPMC3089270 | biostudies-literature
Unknown Crystal structure of bis-[?-bis-(di-phenyl-phosphan-yl)methane-?(2) P:P']-?-chlorido-chlorido-1?Cl-(1-phenyl-thio-urea-2?S)disilver aceto-nitrile hemisolvate.
| S-EPMC4459320 | biostudies-literature
Unknown Crystal structure of [1,3-bis-(di-phenyl-phosphan-yl)propane-?(2) P,P'](N,N'-di-methyl-thio-urea-?S)(thio-cyanato-?N)copper(I).
| S-EPMC4350702 | biostudies-literature
Unknown Crystal structure of (1,3-di-methyl-thio-urea-?S)tris-(tri-phenyl-phosphane-?P)silver(I) acetate.
| S-EPMC4186141 | biostudies-literature
Unknown 1,1'-(Ethane-1,2-di-yl)bis-(3-phenyl-thio-urea).
| S-EPMC3247560 | biostudies-literature
Unknown Crystal structure of (μ-N-allyl-thio-urea-κ(2) S:S)bis-[μ-bis-(di-phenyl-phosphanyl)methane-κ(2) P:P']bis-[bromido-copper(I)] aceto-nitrile disolvate.
| S-EPMC4555395 | biostudies-literature
Unknown Crystal structure of bis-{(<i>S</i>)-1-[2-(di-phenyl-phosphan-yl)ferrocen-yl]-(<i>R</i>)-eth-yl}ammonium bromide di-chloro-methane monosolvate.
| S-EPMC5290554 | biostudies-literature
Unknown Octyl (2E)-2-[2-(di-phenyl-phosphan-yl)benzyl-idene]hydrazinecarbodi-thio-ate.
| S-EPMC4051045 | biostudies-literature
Unknown Tris(N,N-di-methyl-anilinium) hexa-bromido-stannate(IV) bromide.
| S-EPMC3684876 | biostudies-other