Ontology highlight
ABSTRACT:
SUBMITTER: Nimthong-Roldan A
PROVIDER: S-EPMC4438794 | biostudies-literature | 2015 Apr
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Crystallographic communications 20150321 Pt 4
The title complex, [Ag3Br2(C25H22P2)3]Br·C7H8N2S, comprises a trinuclear [Ag3Br2(C25H22P2)3](+) unit, a Br(-) anion and one N,N'-di-methyl-thio-urea mol-ecule (ptu). Three Ag(I) ions are linked via two μ3-bridging Br atoms, leading to a distorted triangular bipyramid with an Ag⋯Ag separation range of 3.1046 (6)-3.3556 (6) Å. The triangular Ag3 arrangement is stabilized by six P atoms from three chelating bis-(di-phenyl-phosphan-yl)methane (dppm) ligands. The Ag(I) ion presents a distorted tetra- ...[more]