Ontology highlight
ABSTRACT:
SUBMITTER: Martinez JI
PROVIDER: S-EPMC4736453 | biostudies-literature | 2016 Jan
REPOSITORIES: biostudies-literature
Angewandte Chemie (International ed. in English) 20151203 3
Allylrhodium species derived from δ-trifluoroboryl β,γ-unsaturated esters undergo chain walking towards the ester moiety. The resulting allylrhodium species react with imines to give products containing two new stereocenters and a Z-alkene. By using a chiral diene ligand, products can be obtained with high enantioselectivities, where a pronounced matched/mismatched effect with the chirality of the allyltrifluoroborate is evident. ...[more]