Ontology highlight
ABSTRACT:
SUBMITTER: Hepburn HB
PROVIDER: S-EPMC4497600 | biostudies-literature | 2014 Oct
REPOSITORIES: biostudies-literature
Angewandte Chemie (International ed. in English) 20140909 43
Allylrhodium species generated from potassium allyltrifluoroborates can undergo isomerization by 1,4-rhodium(I) migration to give more complex isomers, which then react with cyclic imines to provide products with up to three new stereochemical elements. High enantioselectivities are obtained using chiral diene-rhodium complexes. ...[more]