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Crystal structure of chlorido-[trans-1-(di-phenyl-phosphane-thioyl-?S)-2-(di-phenyl-phosphano-yl)ethene]gold(I) di-chloro-methane hemisolvate.

ABSTRACT: The title compound, [AuCl(C26H22OP2S)]·0.5CH2Cl2, crystallizes with a trans-O-P?P-S geometry of the groups either side of the C=C double bond, which prevents any intra-molecular contact between the Au and O atoms. The Au(I) atom exhibits a nearly linear coordination [Cl-Au-S = 177.55?(4)°]. The mol-ecules associate to form broad ribbons parallel to the c axis via two C-H?O, one C-H?Cl(Au) and one Au?Cl inter-action.

SUBMITTER: Taouss C

PROVIDER: S-EPMC4992926 | biostudies-literature | 2016 Jul

REPOSITORIES: biostudies-literature

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Crystal structure of chlorido-[trans-1-(di-phenyl-phosphane-thioyl-κS)-2-(di-phenyl-phosphano-yl)ethene]gold(I) di-chloro-methane hemisolvate.

Taouss Christina C Jones Peter G PG

Acta crystallographica. Section E, Crystallographic communications 20160621 Pt 7

The title compound, [AuCl(C26H22OP2S)]·0.5CH2Cl2, crystallizes with a trans-O-P⋯P-S geometry of the groups either side of the C=C double bond, which prevents any intra-molecular contact between the Au and O atoms. The Au(I) atom exhibits a nearly linear coordination [Cl-Au-S = 177.55 (4)°]. The mol-ecules associate to form broad ribbons parallel to the c axis via two C-H⋯O, one C-H⋯Cl(Au) and one Au⋯Cl inter-action. ...[more]

PMID: 27555951

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