Ontology highlight
ABSTRACT:
SUBMITTER: Pietrusiewicz KM
PROVIDER: S-EPMC6385021 | biostudies-literature | 2019 Feb
REPOSITORIES: biostudies-literature
Molecules (Basel, Switzerland) 20190205 3
A simple, highly efficient synthesis of a series of novel chiral non-racemic rigid tetracyclic phosphorus ligands, applicable in important chemical asymmetric transformations, was performed. In a tandem cross-coupling/C-H bond activation reaction, a well-recognised and readily available ligand <i>(R,R)-</i>NORPHOS was used as the starting material. The palladium complexes of new ligands were obtained and characterised on the example of a crystalline dichloropalladium complex of [(1<i>R</i>,2<i>R ...[more]