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[1,2-Bis(diisopropyl-phosphino)-1,2-dicarba-closo-dodeca-borane-?P,P']dichloridomercury(II).

ABSTRACT: In the title complex, [HgCl(2)(C(14)H(38)B(10)P(2))], the Hg(II) atom is in a distorted HgCl(2)P(2) tetra-hedral coordination environment. The chelation of the Hg atom by two P atoms and two C atoms from the carborane skeleton results in a nearly planar five-membered ring.

SUBMITTER: Su F

PROVIDER: S-EPMC2915082 | biostudies-other | 2007

REPOSITORIES: biostudies-other

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[1,2-Bis(diisopropyl-phosphino)-1,2-dicarba-closo-dodeca-borane-κP,P']dichloridomercury(II).

Su Fangfang F Guo Qingliang Q Dou Jianmin J Li Dacheng D Wang Daqi D

Acta crystallographica. Section E, Structure reports online 20071206 Pt 1

In the title complex, [HgCl(2)(C(14)H(38)B(10)P(2))], the Hg(II) atom is in a distorted HgCl(2)P(2) tetra-hedral coordination environment. The chelation of the Hg atom by two P atoms and two C atoms from the carborane skeleton results in a nearly planar five-membered ring. ...[more]

PMID: 21200491

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(1,2-Dicarba-closo-dodeca-boran-yl)trimethyl-methanaminium iodide.

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