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Bis{1,2-bis-[bis-(3-hydroxy-prop-yl)phosphino]ethane}dichloridoiron(II).

ABSTRACT: In the title compound, [FeCl(2)(C(14)H(32)O(4)P(2))(2)], the Fe(II) atom (site symmetry ) adopts a distorted trans-FeCl(2)P(4) octa-hedral geometry with two P,P'-bidentate ligands in the equatorial positions and two chloride ions in the axial positions. In the crystal, mol-ecules are linked by O-H?O and O-H?Cl hydrogen bonds, generating a three-dimensional network.

SUBMITTER: Crossland JL 

PROVIDER: S-EPMC2979366 | biostudies-literature | 2010 May

REPOSITORIES: biostudies-literature

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Bis{1,2-bis-[bis-(3-hydroxy-prop-yl)phosphino]ethane}dichloridoiron(II).

Crossland Justin L JL   Zakharov Lev N LN   Tyler David R DR  

Acta crystallographica. Section E, Structure reports online 20100522 Pt 6

In the title compound, [FeCl(2)(C(14)H(32)O(4)P(2))(2)], the Fe(II) atom (site symmetry ) adopts a distorted trans-FeCl(2)P(4) octa-hedral geometry with two P,P'-bidentate ligands in the equatorial positions and two chloride ions in the axial positions. In the crystal, mol-ecules are linked by O-H⋯O and O-H⋯Cl hydrogen bonds, generating a three-dimensional network. ...[more]

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