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Bis[2-(1H-benzimidazol-2-yl)phenolato-?N,O]cobalt(II) dimethyl-formamide disolvate.


ABSTRACT: In the crystal structure of the title compound, [Co(C(13)H(9)N(2)O)(2)]·2C(3)H(7)NO, the Co(II) ion is four-coordinated by two N atoms and two O atoms from two deprotonated 2-(1H-benzimidazol-2-yl)phenol ligands in a distorted tetra-hedral geometry. The dimethyl-formamide solvent mol-ecules are found inside a two-dimensional network structure formed by inter-molecular N-H?O hydrogen bonds linking the mol-ecules.

SUBMITTER: He F 

PROVIDER: S-EPMC2959248 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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Bis[2-(1H-benzimidazol-2-yl)phenolato-κN,O]cobalt(II) dimethyl-formamide disolvate.

He Feigang F   Xi Yun Y   Li Jun J   Zhang Fengxing F  

Acta crystallographica. Section E, Structure reports online 20080921 Pt 10


In the crystal structure of the title compound, [Co(C(13)H(9)N(2)O)(2)]·2C(3)H(7)NO, the Co(II) ion is four-coordinated by two N atoms and two O atoms from two deprotonated 2-(1H-benzimidazol-2-yl)phenol ligands in a distorted tetra-hedral geometry. The dimethyl-formamide solvent mol-ecules are found inside a two-dimensional network structure formed by inter-molecular N-H⋯O hydrogen bonds linking the mol-ecules. ...[more]

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