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Chlorido(2-chloro-nicotinato)triphenyl-anti-mony(V).

ABSTRACT: In the title complex, [Sb(C(6)H(5))(3)(C(6)H(3)ClNO(2))Cl], the Sb center has a close to ideal trigonal-bipyramidal geometry, with the phenyl ligands in equatorial positions and the chloride and a carboxyl-ate O atom in axial positions. Weak C-H?O contacts generate dimeric units via crystallographic inversion centres.

SUBMITTER: Quan L

PROVIDER: S-EPMC2959277 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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Chlorido(2-chloro-nicotinato)triphenyl-anti-mony(V).

Quan Li L Yin Handong H Wang Daqi D

Acta crystallographica. Section E, Structure reports online 20080920 Pt 10

In the title complex, [Sb(C(6)H(5))(3)(C(6)H(3)ClNO(2))Cl], the Sb center has a close to ideal trigonal-bipyramidal geometry, with the phenyl ligands in equatorial positions and the chloride and a carboxyl-ate O atom in axial positions. Weak C-H⋯O contacts generate dimeric units via crystallographic inversion centres. ...[more]

PMID: 21201041

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