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Dieth-yl[N-(3-meth-oxy-2-oxidobenzyl-idene)-N'-(oxidomethyl-ene)hydrazine-?O,N,O']tin(IV).

ABSTRACT: In the mol-ecule of the title compound, [Sn(C(2)H(5))(2)(C(9)H(8)N(2)O(3))], the Sn atom is five-coordinated in a distorted trigonal-bipyramidal configuration by two O and one N atoms of the tridentate Schiff base ligand in the equatorial plane, and by two C atoms of ethyl groups in the axial positions. In the crystal structure, inter-molecular C-H?O hydrogen bonds link the mol-ecules into centrosymmetric dimers.

SUBMITTER: Shuja S

PROVIDER: S-EPMC2961818 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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Dieth-yl[N-(3-meth-oxy-2-oxidobenzyl-idene)-N'-(oxidomethyl-ene)hydrazine-κO,N,O']tin(IV).

Shuja Shaukat S Tahir M Nawaz MN Ali Saqib S Khalid Nasir N

Acta crystallographica. Section E, Structure reports online 20080628 Pt 7

In the mol-ecule of the title compound, [Sn(C(2)H(5))(2)(C(9)H(8)N(2)O(3))], the Sn atom is five-coordinated in a distorted trigonal-bipyramidal configuration by two O and one N atoms of the tridentate Schiff base ligand in the equatorial plane, and by two C atoms of ethyl groups in the axial positions. In the crystal structure, inter-molecular C-H⋯O hydrogen bonds link the mol-ecules into centrosymmetric dimers. ...[more]

PMID: 21202810

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