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Dichloridobis(2-dimethyl-amino-1,10-phenanthroline)cadmium(II).

ABSTRACT: In the title complex, [CdCl(2)(C(14)H(13)N(3))(2)], the Cd(II) ion lies on a twofold rotation axis and assumes a distorted octa-hedral CdN(4)Cl(2) coordination geometry. There is a ?-? stacking inter-action between the symmetry-related 1,10-phenanthroline ligands with a centroid-centroid distance of 3.5578?(16)?Å and a perpendicular distance of 3.445?(su?)?Å between the relevant rings.

SUBMITTER: Li HL

PROVIDER: S-EPMC2969892 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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Dichloridobis(2-dimethyl-amino-1,10-phenanthroline)cadmium(II).

Li Hong Liang HL

Acta crystallographica. Section E, Structure reports online 20090829 Pt 9

In the title complex, [CdCl(2)(C(14)H(13)N(3))(2)], the Cd(II) ion lies on a twofold rotation axis and assumes a distorted octa-hedral CdN(4)Cl(2) coordination geometry. There is a π-π stacking inter-action between the symmetry-related 1,10-phenanthroline ligands with a centroid-centroid distance of 3.5578 (16) Å and a perpendicular distance of 3.445 (su?) Å between the relevant rings. ...[more]

PMID: 21577483

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