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Cis-Diaqua-bis(2,2',2''-tripyridylamine)zinc(II) bis-(perchlorate).

ABSTRACT: In the title compound, [Zn(2,2',2''-tpa)(2)(H(2)O)(2)](ClO(4))(2) (2,2',2''-tpa is 2,2',2''-tripyridylamine, C(15)H(12)N(4)), the Zn center lies on a twofold axis and is coordinated octa-hedrally by two water mol-ecules and two bidentate 2,2',2''-tpa ligands. The perchlorate anions are linked to the coordinated water mol-ecules in the complex cations via O-H?O hydrogen bonds.

SUBMITTER: Wang S

PROVIDER: S-EPMC2971047 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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cis-Diaqua-bis(2,2',2''-tripyridylamine)zinc(II) bis-(perchlorate).

Wang Shi S Ding Xuehua X He Wenrui W Huang Wei W

Acta crystallographica. Section E, Structure reports online 20091023 Pt 11

In the title compound, [Zn(2,2',2''-tpa)(2)(H(2)O)(2)](ClO(4))(2) (2,2',2''-tpa is 2,2',2''-tripyridylamine, C(15)H(12)N(4)), the Zn center lies on a twofold axis and is coordinated octa-hedrally by two water mol-ecules and two bidentate 2,2',2''-tpa ligands. The perchlorate anions are linked to the coordinated water mol-ecules in the complex cations via O-H⋯O hydrogen bonds. ...[more]

PMID: 21578160

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