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(2,2'-Bipyridine-?N,N')bis-(N-ethyl-N-phenyl-dithio-carbamato-?S,S')cadmium(II) chloro-form solvate.

ABSTRACT: In the title compound, [Cd(C(9)H(10)NS(2))(2)(C(10)H(8)N(2))]·CHCl(3), the Cd(II) atom exists in an all-cis distorted octa-hedral geometry. Chelation is isobidentate for one dithio-carbamate ligand and anisobidentate for the other. The chloroform solvent mol-ecule is disordered over two positions of equal occupancy.

SUBMITTER: Baba I

PROVIDER: S-EPMC2971268 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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(2,2'-Bipyridine-κN,N')bis-(N-ethyl-N-phenyl-dithio-carbamato-κS,S')cadmium(II) chloro-form solvate.

Baba Ibrahim I Nik Intan Nik Ismail NI Yamin Bohari M BM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20091017 Pt 11

In the title compound, [Cd(C(9)H(10)NS(2))(2)(C(10)H(8)N(2))]·CHCl(3), the Cd(II) atom exists in an all-cis distorted octa-hedral geometry. Chelation is isobidentate for one dithio-carbamate ligand and anisobidentate for the other. The chloroform solvent mol-ecule is disordered over two positions of equal occupancy. ...[more]

PMID: 21578118

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