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(2,2'-Biquinoline-?N,N')dichlorido-iron(II).

ABSTRACT: In the title compound, [FeCl(2)(C(18)H(12)N(2))], the Fe(II) atom is four-coordinated in a distorted tetra-hedral arrangement by an N,N'-bidentate 2,2'-biquinoline ligand and two chloride ions. In the crystal, there are extensive ?-? contacts between the pyridine rings [centroid-centroid distances = 3.7611?(3), 3.7603?(4), 3.5292?(4), 3.5336?(5) and 3.6656?(4)?Å].

SUBMITTER: Rahimi N

PROVIDER: S-EPMC2971346 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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(2,2'-Biquinoline-κN,N')dichlorido-iron(II).

Rahimi Narjes N Safari Nasser N Amani Vahid V Khavasi Hamid Reza HR

Acta crystallographica. Section E, Structure reports online 20091017 Pt 11

In the title compound, [FeCl(2)(C(18)H(12)N(2))], the Fe(II) atom is four-coordinated in a distorted tetra-hedral arrangement by an N,N'-bidentate 2,2'-biquinoline ligand and two chloride ions. In the crystal, there are extensive π-π contacts between the pyridine rings [centroid-centroid distances = 3.7611 (3), 3.7603 (4), 3.5292 (4), 3.5336 (5) and 3.6656 (4) Å]. ...[more]

PMID: 21578122

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