Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Tris(N-benzyl-N-methyl-dithio-carbamato-?S,S')(1,10-phenanthroline-?N,N')europium(III).

ABSTRACT: In the title compound, [Eu(C(9)H(10)NS(2))(3)(C(12)H(8)N(2))], the Eu(III) atom exists in a distorted square-anti-prismatic coordination geometry. Both dithio-carbamate and the N-heterocyclic ligands function in a chelating mode.

SUBMITTER: Baba I

PROVIDER: S-EPMC2971428 | biostudies-other | 2009

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

Tris(N-benzyl-N-methyl-dithio-carbamato-κS,S')(1,10-phenanthroline-κN,N')europium(III).

Baba Ibrahim I Raya Indah I Yamin Bohari M BM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20091017 Pt 11

In the title compound, [Eu(C(9)H(10)NS(2))(3)(C(12)H(8)N(2))], the Eu(III) atom exists in a distorted square-anti-prismatic coordination geometry. Both dithio-carbamate and the N-heterocyclic ligands function in a chelating mode. ...[more]

PMID: 21578126

Similar Datasets

Bis(N-isopropyl-N-methyl-dithio-carbamato-?S,S')(1,10-phenanthroline-?N,N')zinc.

Project description:The Zn(II) atom in the title compound, [Zn(C(5)H(10)NS(2))(2)(C(12)H(8)N(2))], exists in a distorted cis-octa-hedral N(2)S(4) donor set defined by two chelating dithio-carbamate anions as well as a 1,10-phenanthroline ligand. Each of the ligands coordinates in a symmetric mode. The crystal packing is stabilized by weak C-H?S, C-H??(ZnS(2)C) and ?-? [ring centroid distance between centrosymmetrically related pyridyl rings = 3.5955?(13)?Å] inter-actions.

| S-EPMC3089284 | biostudies-literature

Bis(μ-N-benzyl-N-methyl-dithio-carbamato)-1:2κS,S':S';1:2κS:S,S'-bis-[bis-(N-benzyl-N-methyl-dithio-carbamato-κS,S')thallium(III)].

Project description:The molecule of the dinuclear title compound, [Tl(2)(C(9)H(10)NS(2))(6)], possesses a crystallographically imposed centre of symmetry. Each Tl(III) atom is seven-coordinated by S atoms of four different dithio-carbamate anions in a distorted penta-gonal-bipyramidal coordination geometry. The crystal structure is stabilized by a C-H⋯S hydrogen-bond inter-action linking complex mol-ecules into chains running parallel to the b axis. Intramolecular C-H⋯S hydrogen bonds are also present.

| S-EPMC2961943 | biostudies-literature

Bis(N,N-diethyl-dithio-carbamato)(1,10-phenanthroline)cobalt(III) tetra-fluorido-borate.

Project description:The cationic complex in the structure of the title compound, [Co(Et(2)NCS(2))(2)(C(12)H(8)N(2))]BF(4), has a Co(III) atom with a distorted octa-hedral coordination formed by four S atoms of two diethyl-dithio-carbamate and two N atoms of 1,10-phenanthroline ligands. The crystal structure features head-to-tail stacking of the phenanthroline ligands. The tetra-fluorido-borate anions are positioned in the channels between the cation stacks running along the a axis, and form weak C-H?F interactions.

| S-EPMC2961857 | biostudies-other

Bis(N-sec-butyl-N-n-propyl-dithio-carbamato-κS,S')(1,10-phenanthroline-κN,N')zinc(II).

Project description:Two independent but very similar mol-ecules comprise the asymmetric unit of the title compound, [Zn(C(8)H(16)NS(2))(2)(C(12)H(8)N(2))]. The N(2)S(4) donor set about Zn is defined by two symmetrically chelating dithio-carbamate ligands and a 1,10-phenanthroline ligand. Distortions from the ideal octa-hedral coordination geometry arise from the restricted bite angles of the ligands. The main feature of the crystal packing is the formation of tetra-meric supra-molecular aggregates mediated by C-H⋯S inter-actions. Disorder was found in each of the sec-butyl groups. This was resolved over two positions in each case with the major components of the disorder having site occupancies in the range 0.551 (6)-0.725 (5).

| S-EPMC3008025 | biostudies-literature

1,10-Phenanthroline-dithio-oxamide (2/1).

Project description:The asymmetric unit of the title compound, C(12)H(8)N(2)·0.5C(2)H(4)N(2)S(2), contains one 1,10-phenanthroline mol-ecule and a half-mol-ecule of dithio-oxamide, which lies across a crystallographic inversion center. The 1,10-phenanthroline unit is not strictly planar, with dihedral angles between the central benzene ring and the pyridine rings of 1.42?(10) and 1.40?(10)°. In the crystal structure, two 1,10-phenanthroline mol-ecules are linked together by one dithio-oxamide via inter-molecular N-H?N hydrogen bonds.

| S-EPMC2979584 | biostudies-literature

Tris(nitrato-κO,O')bis-(1,10-phenanthroline-κN,N')holmium(III).

Project description:In the title compound, [Ho(NO(3))(3)(C(12)H(8)N(2))(2)], the ten-coordinate Ho(III) ion is chelated by four N atoms from two phenanthroline (phen) ligands and six O atoms from three bidentate nitrate groups. The environment around the Ho atom can be described as a distorted bicapped square anti-prism. Two phenanthroline ligands form a dihedral angle of 43.72 (13)°. Short inter-molecular distances between the centroids of the six-membered rings [3.6887 (14)-3.8374 (16) Å] indicate the existence of π-π inter-actions, which link the mol-ecules into stacks extended in the [10] direction. The crystal packing is further stabilized by weak inter-molecular C-H⋯O hydrogen bonds.

| S-EPMC2961938 | biostudies-literature

Tris(1,10-phenanthroline-?(2)N,N')iron(II) bis-[(1,10-phenanthroline-?(2)N,N')tetra-kis-(thio-cyanato-?N)chromate(III)] acetonitrile tris-olvate monohydrate.

Project description:Single crystals of the title heterometallic compound, [Fe(C(12)H(8)N(2))(3)][Cr(NCS)(4)(C(12)H(8)N(2))](2)·3CH(3)CN·H(2)O or [Fe(Cphen)(3)][Cr(NCS)(4)(phen)](2)·3CH(3)CN·H(2)O, were pre-pared using the one-pot open-air reaction of iron powder, Reineckes salt and 1,10-phenanthroline (phen) in acetonitrile. The asymetric unit consists of an [Fe(phen)(3)](2+) cation, two [Cr(phen)(NCS)(4)](-) anions, three acetonitrile solvent mol-ecules and a water mol-ecule. The Fe and Cr atoms both show a slightly distorted octa-hedral FeN(6) and CrN(6) coordination geometry with adjacent angles in the range 79.67?(12)-95.21?(12)°. No classical hydrogen bonding involving the water molecule is observed.

| S-EPMC3344293 | biostudies-literature

Redetermination of tris-(N,N-diethyl-dithio-carbamato)anti-mony(III).

Project description:The title compound, [Sb(C(5)H(10)NS(2))(3)], was synthesized from Sb(2)O(3), diethyl-amine, carbon dis-ulfide, hydro-chloric acid and sodium hydroxide. The structure has been published previously but H atoms were not included in the model [Raston & White (1976 ?). Chem. Soc. Dalton Trans. p. 791]. The current determination has significantly higher precision than the original work. The complex has three ligands. The Sb atom is coordinated by three bidentate diethyl-dithio-carbamate groups, two in an almost planar fashion and the third perpendicular to that plane with a dihedral angle of 86.429?(13)°. One ethyl group is disordered over two positions of equal occupancy.

| S-EPMC2968436 | biostudies-other

(N,N-Diethyl-dithio-carbamato-?S,S')iodido(1,10-phenanthroline-?N,N')copper(II).

Project description:The copper(II) atom in the title compound, [Cu(C(5)H(10)NS(2))I(C(12)H(8)N(2))], is chelated by the N-heterocycle and the dithio-carbamate anion in a slightly distorted tetragonal coordination. The tetragonal-pyramidal coorination is completed by the iodine atom in the apical position. One ethyl group is disordered over two positions with site occupancies of 0.31?(2) and 0.69?(2).

| S-EPMC2970455 | biostudies-other

Luminescent Complexes of Europium (III) with 2-(Phenylethynyl)-1,10-phenanthroline: The Role of the Counterions.

Project description:New antenna ligand, 2-(phenylethynyl)-1,10-phenanthroline (PEP), and its luminescent Eu (III) complexes, Eu(PEP)2Cl3 and Eu(PEP)2(NO3)3, are synthesized and characterized. The synthetic procedure applied is based on reacting of europium salts with ligand in hot acetonitrile solutions in molar ratio 1 to 2. The structure of the complexes is refined by X-ray diffraction based on the single crystals obtained. The compounds [Eu(PEP)2Cl3]·2CH3CN and [Eu(PEP)2(NO3)3]∙2CH3CN crystalize in monoclinic space group P21/n and P21/c, respectively, with two acetonitrile solvent molecules. Intra- and inter-ligand π-π stacking interactions are present in solid stat and are realized between the phenanthroline moieties, as well as between the substituents and the phenanthroline units. The optical properties of the complexes are investigated in solid state, acetonitrile and dichloromethane solution. Both compounds exhibit bright red luminescence caused by the organic ligand acting as antenna for sensitization of Eu (III) emission. The newly designed complexes differ in counter ions in the inner coordination sphere, which allows exploring their influence on the stability, molecular and supramolecular structure, fluorescent properties and symmetry of the Eu (III) ion. In addition, molecular simulations are performed in order to explain the observed experimental behavior of the complexes. The discovered structure-properties relationships give insight on the role of the counter ions in the molecular design of new Eu (III) based luminescent materials.

| S-EPMC8658859 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data