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Trans-Bis[4-amino-N-(pyrimidin-2-yl)benzene-sulfonamidato]dipyridine-nickel(II) hemihydrate.

ABSTRACT: The asymmetric unit of the title compound, [Ni(C(10)H(9)N(4)O(2)S)(2)(C(5)H(5)N)(2)]·0.5H(2)O, contains the distorted octa-hedral trans-[Ni(sdz)(2)(py)(2)] (sdz is the sulfadiazine anion and py is pyridine) complex mol-ecule and half of a water mol-ecule. A three-dimensional network is generated by N-H?O and O-H?O hydrogen bonds and C-H?O inter-actions between the complex and the water mol-ecules.

SUBMITTER: Wang YF

PROVIDER: S-EPMC2971836 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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trans-Bis[4-amino-N-(pyrimidin-2-yl)benzene-sulfonamidato]dipyridine-nickel(II) hemihydrate.

Wang Yan-Fei YF Li Fu-Xing FX Peng Yan Y Chen Zhen-Feng ZF Liang Hong H

Acta crystallographica. Section E, Structure reports online 20091114 Pt 12

The asymmetric unit of the title compound, [Ni(C(10)H(9)N(4)O(2)S)(2)(C(5)H(5)N)(2)]·0.5H(2)O, contains the distorted octa-hedral trans-[Ni(sdz)(2)(py)(2)] (sdz is the sulfadiazine anion and py is pyridine) complex mol-ecule and half of a water mol-ecule. A three-dimensional network is generated by N-H⋯O and O-H⋯O hydrogen bonds and C-H⋯O inter-actions between the complex and the water mol-ecules. ...[more]

PMID: 21578614

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