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(E)-2-[(4-Fluoro-phen-yl)imino-meth-yl]-5-methoxy-phenol.

ABSTRACT: In the mol-ecule of the title compound, C(14)H(12)FNO(2), the aromatic rings are oriented at a dihedral angle of 48.17?(1)°. An intra-molecular O-H?N hydrogen bond results in the formation of a six-membered ring. The title mol-ecule is a phenol-imine tautomer, as evidenced by the C-O [1.351?(3)?Å], C-N [1.282?(3)?Å], and C-C [1.416?(3)-1.445?(3)?Å] bond lengths. In the crystal, mol-ecules are linked by inter-molecular C-H?? inter-actions.

SUBMITTER: Albayrak C

PROVIDER: S-EPMC2979905 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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(E)-2-[(4-Fluoro-phen-yl)imino-meth-yl]-5-methoxy-phenol.

Albayrak Ciğdem C Ozek Arzu A Koşar Başak B Odabaşoğlu Mustafa M Büyükgüngör Orhan O

Acta crystallographica. Section E, Structure reports online 20100109 Pt 2

In the mol-ecule of the title compound, C(14)H(12)FNO(2), the aromatic rings are oriented at a dihedral angle of 48.17 (1)°. An intra-molecular O-H⋯N hydrogen bond results in the formation of a six-membered ring. The title mol-ecule is a phenol-imine tautomer, as evidenced by the C-O [1.351 (3) Å], C-N [1.282 (3) Å], and C-C [1.416 (3)-1.445 (3) Å] bond lengths. In the crystal, mol-ecules are linked by inter-molecular C-H⋯π inter-actions. ...[more]

PMID: 21579745

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