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Di-?-chlorido-bis-{[4-chloro-2-(dimethyl-amino-meth-yl)phenyl-?C,N]palladium(II)}.

ABSTRACT: The title compound, [Pd(2)(C(9)H(11)ClN)(2)Cl(2)], consists of two Pd atoms which are bridged by two Cl atoms, forming a centrosymmetric binuclear complex with a square-planar coordination for each of the Pd atoms. The Pd atom is chelated by one N and one C atom from a 4-chloro-2-(dimethyl-amino-meth-yl)phenyl ligand, forming a five-membered ring (N-Pd-C-C-C). In the crystal structure, weak C-H ?Cl hydrogen bonds link the mol-ecules in rows.

SUBMITTER: Sang Y

PROVIDER: S-EPMC2983531 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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Di-μ-chlorido-bis-{[4-chloro-2-(dimethyl-amino-meth-yl)phenyl-κC,N]palladium(II)}.

Sang Yankui Y Hong Qiaomin Q Qiu Wenwei W Liu Qiancai Q Yang Fan F

Acta crystallographica. Section E, Structure reports online 20100203 Pt 3

The title compound, [Pd(2)(C(9)H(11)ClN)(2)Cl(2)], consists of two Pd atoms which are bridged by two Cl atoms, forming a centrosymmetric binuclear complex with a square-planar coordination for each of the Pd atoms. The Pd atom is chelated by one N and one C atom from a 4-chloro-2-(dimethyl-amino-meth-yl)phenyl ligand, forming a five-membered ring (N-Pd-C-C-C). In the crystal structure, weak C-H ⋯Cl hydrogen bonds link the mol-ecules in rows. ...[more]

PMID: 21580207

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