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Dichlorido[(S)-N-(1-phenyl-ethyl-idene)-1-(pyridin-2-yl)ethanamine-?N,N']zinc(II) dichloro-methane solvate.

ABSTRACT: In the title compound, [ZnCl(2)(C(15)H(16)N(2))]·CH(2)Cl(2), the Zn(II) atom has a distorted tetra-hedral coordination by two Cl atoms and two N atoms from the organic ligand [the average Zn-N and Zn-Cl bond lengths are 2.060?(4)?Å and Zn-Cl = 2.179?(16)?Å, respectively]. The dihedral angle between the N-Zn-N and Cl-Zn-Cl planes is 89.9?(1)°. The phenyl ring forms a dihedral angle of 40.6?(5)° with the imine plane.

SUBMITTER: Nayab S

PROVIDER: S-EPMC3007472 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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Dichlorido[(S)-N-(1-phenyl-ethyl-idene)-1-(pyridin-2-yl)ethanamine-κN,N']zinc(II) dichloro-methane solvate.

Nayab Saira S Paek Seung-Min SM Jeong Jong Hwa JH

Acta crystallographica. Section E, Structure reports online 20100731 Pt 8

In the title compound, [ZnCl(2)(C(15)H(16)N(2))]·CH(2)Cl(2), the Zn(II) atom has a distorted tetra-hedral coordination by two Cl atoms and two N atoms from the organic ligand [the average Zn-N and Zn-Cl bond lengths are 2.060 (4) Å and Zn-Cl = 2.179 (16) Å, respectively]. The dihedral angle between the N-Zn-N and Cl-Zn-Cl planes is 89.9 (1)°. The phenyl ring forms a dihedral angle of 40.6 (5)° with the imine plane. ...[more]

PMID: 21588102

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