Browse
Submit Data
Databases
API
Help

Dataset Information

5 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

1-Chloro-methyl-1,4-diazo-niabicyclo-[2.2.2]octane bis-(hexa-fluoro-phosphate).

ABSTRACT: In the crystal structure of the title compound, C(7)H(15)ClN(2) (2+)·2PF(6) (-), the cations and anions are linked by inter-molecular N-H?F hydrogen bonds.

SUBMITTER: Zhu RQ

PROVIDER: S-EPMC3051799 | biostudies-other | 2011

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

1-Chloro-methyl-1,4-diazo-niabicyclo-[2.2.2]octane bis-(hexa-fluoro-phosphate).

Zhu Run-Qiang RQ

Acta crystallographica. Section E, Structure reports online 20110112 Pt 2

In the crystal structure of the title compound, C(7)H(15)ClN(2) (2+)·2PF(6) (-), the cations and anions are linked by inter-molecular N-H⋯F hydrogen bonds. ...[more]

PMID: 21523027

Similar Datasets

1,4-Diazo-niabicyclo-[2.2.2]octane bis-(2-chloro-benzoate).

Project description:The title compound, C(6)H(14)N(2) (2+)·2C(7)H(4)ClO(2) (-), contains trimeric units linked by N-H?O hydrogen bonds. The carboxyl-ate groups of the 2-chloro-benzoate anions form dihedral angles of 66.1?(1) and 76.1?(1)° with the respective chloro-benzene rings to which they are bound. The hydrogen-bonded trimers are arranged in layers in the (200) planes and the chloro-benzoate anions form edge-to-face inter-actions between layers, with dihedral angles of 61.9?(1) and 49.8?(1)° and centroid-centroid distances of 4.85?(1) and 4.65?(1)?Å, respectively, for two crystallographically distinct inter-actions.

| S-EPMC2962050 | biostudies-literature

1,4-Diazo-niabicyclo-[2.2.2]octane hexa-aqua-magnesium bis-(sulfate).

Project description:In the title compound, (C(6)H(14)N(2))[Mg(H(2)O)(6)](SO(4))(2), the Mg(II) ion, lying on an inversion center, is coordinated by six water mol-ecules in a slightly distorted octa-hedral geometry. The 1,4-diazo-niabicyclo-[2.2.2]octane cation is located about a twofold rotation axis. Inter-molecular N-H⋯O and O-H⋯O hydrogen bonds link the cations and the anions into a three-dimensional network.

| S-EPMC3051936 | biostudies-literature

1-Chloro-methyl-1,4-diazo-niabicyclo[2.2.2]octane tetra-chloridocuprate(II).

Project description:In the crystal structure of the title compound, (C(7)H(15)ClN(2))[CuCl(4)], a weak inter-molecular N-H?Cl hydrogen bond is observed between the organic dication and the tetrahedral [CuCl(4)](2-) anion. The organic dication is distorted, as indicated by the N-C-C-N torsion angles, which range from 16.76?(4) to 19.54?(3)°.

| S-EPMC3152011 | biostudies-literature

1,4-Diazo-niabicyclo-[2.2.2]octane bis-(2,4,6-trinitro-phenolate).

Project description:In the title compound, C(6)H(14)N(2) (2+)·2C(6)H(2)N(3)O(7) (-), the cation possesses crystallographically imposed twofold rotation symmetry. In the crystal structure, the cation and anions are linked into a trimeric aggregate by inter-molecular N-H⋯O hydrogen bonds. The trimeric units are further connected by π-π inter-actions [centroid-centroid distances = 3.507 (2)-3.660 (3) Å], forming layers parallel to the bc plane.

| S-EPMC3006919 | biostudies-literature

A new dabco-templated metal sulfate: 1,4-diazo-niabicyclo-[2.2.2]octane hexa-aqua-cadmium bis-(sulfate).

Project description:The title double mol-ecular salt, (C(6)H(14)N(2))[Cd(H(2)O)(6)](SO(4))(2), is an isostructure of its Mn and Co analogues. The Cd(II) atom adopts a near-regular CdO(6) octa-hedral coordination geometry. The crystal structure can be described as an alternation of cationic and anionic layers along [010], and numerous O-H⋯O and N-H⋯O hydrogen bonds are observed. No thermal anomalies corresponding to possible phase transitions were observed in DSC (differential scanning calorimetry) measurements and the 93 K structure is almost the same as the room-temperature structure.

| S-EPMC3379097 | biostudies-literature

1,4-Diazo-niabicyclo-[2.2.2]octane terephthalate.

Project description:In the title compound, C(6)H(14)N(2+)·C(8)H(4)O(4) (2-), the protonated 1,4-diazo-niabicyclo-[2.2.2]octane cations and the deprotonated terephthalate anions are alternately linked by N-H?O hydrogen bonds into chains.

| S-EPMC2960572 | biostudies-literature

1-Cyano-methyl-1,4-diazo-niabicyclo-[2.2.2]octane tetra-chloridomanganate(II).

Project description:In the crystal structure of the title compound, (C(8)H(15)N(3))[MnCl(4)], the Mn atom is coordinated by four chloride ligands in a slightly distorted tetra-hedral geometry. Each [MnCl(4)](2-) anion is connected to the 1-cyano-methyl-1,4-diazo-niabicyclo-[2.2.2]octane dications by N-H?Cl hydrogen bonds, forming chains parallel to [001].

| S-EPMC3009148 | biostudies-literature

1-Cyano-methyl-1,4-diazo-niabicyclo-[2.2.2]octane tetra-chloridocobaltate(II).

Project description:In the title salt, (C(8)H(15)N(3))[CoCl(4)], the four chloride anions coordinate the Co(II) ion in a distorted tetra-hedral geometry. In the crystal, N-H?Cl hydrogen bonds link cations and anions into chains running along the c axis. The crystal packing is further stabilized by weak C-H?Cl and C-H?N inter-actions.

| S-EPMC3344387 | biostudies-literature

1-Cyano-methyl-1,4-diazo-niabicyclo-[2.2.2]octane tetra-chloridocadmate(II).

Project description:In the title salt, (C(8)H(15)N(3))[CdCl(4)], four Cl atoms coordinate the Cd(II) atom in a slightly distorted tetra-hedral geometry. In the crystal, each [CdCl(4)](2-) anion is connected to the 1-cyano-methyl-1,4-diazo-niabicyclo-[2.2.2]octane dications by N-H?Cl hydrogen bonds, forming chains parallel to [001]. C-H?Cl inter-actions also occur.

| S-EPMC3344406 | biostudies-literature

1-Cyano-methyl-1,4-diazo-niabicyclo-[2.2.2]octane tetra-chloridocuprate(II).

Project description:In the crystal structure of the title compound, (C(8)H(15)N(3))[CuCl(4)], the cations and anions, in which the Cu(II) atom is tetra-hedrally coordinated, are linked via N-H?Cl hydrogen bonds into chains that are elongated in the c-axis direction.

| S-EPMC3011750 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data