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Cis-(Dimethyl sulfoxide-?O)[N'-(3-eth-oxy-2-oxidobenzyl-idene-?O)-2-hy-droxy-benzohydrazidato-?N',O]dioxido-molybdenum(VI).

ABSTRACT: The coordination geometry at the Mo(VI) atom in the title compound, [Mo(C(16)H(14)N(2)O(4))O(2)(C(2)H(6)OS)], is distorted octa-hedral. The phenolate O, imino N, oxide O from the enolized carbonyl group and one of the terminal O atoms form the equatorial plane; the axial positions are occupied by the other terminal O atom of the dioxidomolybdenum group and the donor O atom of DMSO. The O=Mo=O angle is 105.31?(6)°. An intra-molecular O-H?N hydrogen bond and weak inter-molecular C-H?O hydrogen bonds are present in the structure.

SUBMITTER: Ngan NK

PROVIDER: S-EPMC3152017 | biostudies-other | 2011 Jul

REPOSITORIES: biostudies-other

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cis-(Dimethyl sulfoxide-κO)[N'-(3-eth-oxy-2-oxidobenzyl-idene-κO)-2-hy-droxy-benzohydrazidato-κN',O]dioxido-molybdenum(VI).

Ngan Ngui Khiong NK Lo Kong Mun KM Richard Wong Chee Seng CS

Acta crystallographica. Section E, Structure reports online 20110604 Pt 7

The coordination geometry at the Mo(VI) atom in the title compound, [Mo(C(16)H(14)N(2)O(4))O(2)(C(2)H(6)OS)], is distorted octa-hedral. The phenolate O, imino N, oxide O from the enolized carbonyl group and one of the terminal O atoms form the equatorial plane; the axial positions are occupied by the other terminal O atom of the dioxidomolybdenum group and the donor O atom of DMSO. The O=Mo=O angle is 105.31 (6)°. An intra-molecular O-H⋯N hydrogen bond and weak inter-molecular C-H⋯O hydrogen bon ...[more]

PMID: 21836856

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