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Trans-Bis(N'-isopropyl-idene-benzo-hydrazidato-?N',O)bis-(pyridine-?N)nickel(II).

ABSTRACT: The complex mol-ecule of the title compound, [Ni(C(10)H(11)N(2)O)(2)(C(5)H(5)N)(2)], has a crystallographically imposed centre of symmetry. The Ni(II) atom is coordinated in a distorted octa-hedral geometry by the O and N atoms of two trans arranged anionic bidentate hydrazone ligands forming the equatorial plane and by the N atoms of two pyridine mol-ecules at the axial positions. In the crystal, inter-molecular C-H?N hydrogen bonds link the mol-ecules into columns parallel to the b axis.

SUBMITTER: Zheng CZ 

PROVIDER: S-EPMC3152089 | biostudies-other | 2011 Jul

REPOSITORIES: biostudies-other

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trans-Bis(N'-isopropyl-idene-benzo-hydrazidato-κN',O)bis-(pyridine-κN)nickel(II).

Zheng Chang-Zheng CZ   Wang Liang L   Liu Juan J  

Acta crystallographica. Section E, Structure reports online 20110625 Pt 7

The complex mol-ecule of the title compound, [Ni(C(10)H(11)N(2)O)(2)(C(5)H(5)N)(2)], has a crystallographically imposed centre of symmetry. The Ni(II) atom is coordinated in a distorted octa-hedral geometry by the O and N atoms of two trans arranged anionic bidentate hydrazone ligands forming the equatorial plane and by the N atoms of two pyridine mol-ecules at the axial positions. In the crystal, inter-molecular C-H⋯N hydrogen bonds link the mol-ecules into columns parallel to the b axis. ...[more]

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