Unknown

Dataset Information

0

Bis(acetato-?O)bis-(pyridine-2-aldoxime-?(2)N,N')nickel(II).

ABSTRACT: In the mononuclear title compound, [Ni(CH(3)COO)(2)(C(6)H(6)N(2)O)(2)], the Ni(II) atom is coordinated by two pyridine-2-aldoxime (PaoH) ligands and two acetate groups, with cis coordination for the pairs of identical ligands. While each acetate group binds to the Ni(II) atom by one O atom, each PaoH chelates the Ni(II) atom through two N atoms. The O atom on PaoH is not deprotonated and does not participate in bonding to the Ni(II) atom. Thus, the Ni(II) atom exhibits an octa-hedral environment. Intra-molecular O-H?O hydrogen-bonding inter-actions and inter-molecular C-H?O hydrogen-bonding inter-actions are present in the structure. Adjacent mol-ecules pack along [100] through van der Waals forces.

SUBMITTER: Si Y 

PROVIDER: S-EPMC3344309 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Bis(acetato-κO)bis-(pyridine-2-aldoxime-κ(2)N,N')nickel(II).

Si Youtao Y  

Acta crystallographica. Section E, Structure reports online 20120413 Pt 5

In the mononuclear title compound, [Ni(CH(3)COO)(2)(C(6)H(6)N(2)O)(2)], the Ni(II) atom is coordinated by two pyridine-2-aldoxime (PaoH) ligands and two acetate groups, with cis coordination for the pairs of identical ligands. While each acetate group binds to the Ni(II) atom by one O atom, each PaoH chelates the Ni(II) atom through two N atoms. The O atom on PaoH is not deprotonated and does not participate in bonding to the Ni(II) atom. Thus, the Ni(II) atom exhibits an octa-hedral environment  ...[more]

Similar Datasets

Unknown Tetra-pyridine-bis(trichloro-acetato)nickel(II).
| S-EPMC2970073 | biostudies-literature
Unknown Bis(acetato-?O)bis-(2-pyridine-aldoxime-?(2)N,N')cadmium.
| S-EPMC3414138 | biostudies-literature
Unknown Bis(acetato-?O,O')bis-(2-amino-pyridine-?N)nickel(II).
| S-EPMC2915125 | biostudies-literature
Unknown Bis(acetato-?O,O')bis-[4-(dimethyl-amino)-pyridine-?N]copper(II).
| S-EPMC3051772 | biostudies-literature
Unknown Tetra-?-acetato-bis-[(pyridine N-oxide)copper(II)](Cu-Cu).
| S-EPMC2977355 | biostudies-literature
Unknown Tetra-aqua-bis-(pyridine-κN)nickel(II) dinitrate.
| S-EPMC3006910 | biostudies-literature
Unknown trans-Bis(acetato-?O)bis-(2-amino-ethanol-?(2)N,O)nickel(II).
| S-EPMC3344318 | biostudies-literature
Unknown Bis(3-hydroxy-phenyl-acetato-?O,O')bis-(1H-imidazole-?N)nickel(II).
| S-EPMC2968559 | biostudies-literature
Unknown Tetra-aqua-bis[2-(2,4-dichloro-phen-oxy)acetato]nickel(II).
| S-EPMC2969976 | biostudies-literature
Unknown (Acetato-?(2)O,O')(acetato-?O)bis(2-amino-3-methyl-pyridine-?N(1))cobalt(II).
| S-EPMC3470146 | biostudies-literature