Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

(Acetyl-acetonato-?O,O')bis-[2-(naphth[1,2-d][1,3]oxazol-2-yl)phenyl-?C,N]iridium(III).

ABSTRACT: In the crystal structure of the title compound, [Ir(C(17)H(10)NO)(2)(C(5)H(7)O(2))], the Ir(III) atom is O,O'-chelated by the acetyl-acetonate group and C,N-chelated by the 2-aryl-naphth[1,2-d]oxazole groups. The six-coordinate metal atom displays a distorted octa-hedral geometry.

SUBMITTER: Yin G

PROVIDER: S-EPMC3200896 | biostudies-other | 2011 Sep

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

(Acetyl-acetonato-κO,O')bis-[2-(naphth[1,2-d][1,3]oxazol-2-yl)phenyl-κC,N]iridium(III).

Yin Guojie G

Acta crystallographica. Section E, Structure reports online 20110827 Pt 9

In the crystal structure of the title compound, [Ir(C(17)H(10)NO)(2)(C(5)H(7)O(2))], the Ir(III) atom is O,O'-chelated by the acetyl-acetonate group and C,N-chelated by the 2-aryl-naphth[1,2-d]oxazole groups. The six-coordinate metal atom displays a distorted octa-hedral geometry. ...[more]

PMID: 22058890

Similar Datasets

(Acetyl-acetonato-?O,O')bis-[5-meth-oxy-2-(naphth[1,2-d][1,3]oxazol-2-yl)phenyl-?C,N]iridium(III).

Project description:In the title compound, [Ir(C(18)H(12)NO(2))(2)(C(5)H(7)O(2))], the Ir atom is O,O'-chelated by the acetyl-acetonate group and C,N-chelated by the 2-aryl-naphth[1,2-d]oxazole groups. The six-coordinate metal atom displays a distorted octa-hedral geometry. Intra-molecular C-H?O hydrogen bonds occur. In the crystal, inter-molecular C-H?O hydrogen bonds link the mol-ecules into columns parallel to the b axis.

| S-EPMC3201473 | biostudies-literature

Bis(acetyl-acetonato-?O,O')-aqua-(diacetyl-methanido-?C)iridium(III).

Project description:In the crystal structure of the title compound, [Ir(C(5)H(7)O(2))(3)(H(2)O)], the Ir(III) atom is six-coordinated and situated in a slightly distorted octa-hedral environment. The complex contains both Ir-O and Ir-C bonds and was isolated from a reaction mixture of IrCl(3)(H(2)O)(x), pentane-2,5-dione and NaHCO(3). O-H?O hydrogen bonding between the water molecules and the carbonyl O atoms of adjacent molecules leads to a layered motif extending parallel to (010).

| S-EPMC2970352 | biostudies-literature

(Acetyl-acetonato-?O,O')bis-[2-(5-methyl-3-phenyl-pyrazin-2-yl-?N)phen-yl-?C]iridium(III).

Project description:In the title complex, [Ir(C(17)H(13)N(2))(2)(C(5)H(7)O(2))], the Ir(III) atom is hexa-coordinated in a distorted octa-hedral geometry by two C,N-bidentate 2-(5-methyl-3-phenyl-pyrazin-2-yl)phenyl (mdpp) ligands and one O,O-bidentate acetyl-acetonate ligand. The dihedral angles between the phenyl rings and the pyrazine ring are 9.56?(14) and 58.99?(14)° for one mdpp ligand and 9.34?(14) and 79.94?(15)° for the other.

| S-EPMC3297258 | biostudies-literature

(Acetyl-acetonato-κ(2)O,O')bis-{5-fluoro-2-[3-(4-fluoro-phen-yl)pyrazin-2-yl]phenyl-κ(2)N(1),C(1)}iridium(III).

Project description:In the title complex, [Ir(C(16)H(9)F(2)N(2))(2)(C(5)H(7)O(2))], the Ir(III) atom, lying on a twofold rotation axis, is hexa-coordinated in a distorted octa-hedral geometry by two C,N-bidentate 5-fluoro-2-[3-(4-fluoro-phen-yl)pyrazin-2-yl]phenyl ligands and one O,O'-bidentate acetyl-acetonate ligand. The dihedral angles between the benzene rings and the pyrazine ring are 14.66 (8) and 49.76 (12)°.

| S-EPMC3414137 | biostudies-literature

Bis(acetyl-acetonato-κO,O')(methanol-κO)(thio-cyanato-κN)manganese(III).

Project description:In the title complex, [Mn(C(5)H(7)O(2))(2)(NCS)(CH(4)O)], the Mn(III) atom has a slightly distorted octa-hedral coordination formed by five O atoms and one N atom. The equatorial positions are occupied by four O atoms of two acetyl-acetonate ligands, while the axial positions are occupied by the N atom of the thio-cyanate anion and the O atom of the methanol mol-ecule. In the crystal structure, complex mol-ecules are linked by an inter-molecular O-H⋯S hydrogen bond, forming a chain running along [101].

| S-EPMC2959789 | biostudies-literature

Aqua-[N-(1-naphth-yl)acetamido-κN]bis-[2-(2-pyrid-yl)phenyl-κN,C]iridium(III) ethyl-ene glycol hemisolvate.

Project description:In the title compound, [Ir(C(11)H(8)N)(2)(C(12)H(10)NO)(H(2)O)]·0.5C(2)H(6)O(2), the iridium center is coordinated by two N atoms and two C atoms from two 2-(2-pyrid-yl)phenyl (ppy) ligands, one N atom from the N-(1-naphth-yl)acetamide ligand and one water O atom, forming a distorted octa-hedral environment. Mol-ecules are linked by inter-molecular O-H⋯O hydrogen bonds formed by the coordinated water mol-ecule and the amide O atom of the N-(1-naphth-yl)acetamide ligands.

| S-EPMC2961167 | biostudies-literature

Bis[2-(1,3-benzo-thia-zol-2-yl)phenyl-?(2) C (1),N][1,3-bis-(4-bromo-phen-yl)propane-1,3-dionato-?(2) O,O']iridium(III).

Project description:The title complex, [Ir(C15H9Br2O2)(C13H8NS)2], lies about a crystallographic twofold rotation axis passing through the Ir(III) atom and the central C atom of the bis-(bromo-phen-yl)propane-1,3-dionate ligand. The Ir(III) atom adopts a distorted octa-hedral geometry coordinated by two N atoms in the axial positions, and two C and two O atoms in the equatorial plane. The dihedral angle between the two thia-zole ring systems in the complex is 77.45?(10)°.

| S-EPMC3793684 | biostudies-literature

Crystal structure of 1,3-bis-{[4-(acetyl-sulfanyl)phenyl]ethynyl}azulene.

Project description:In the title compound, C30H20O2S2, the dihedral angles between the central azulene ring system (r.m.s. deviation = 0.039 Å) and the pendant benzene rings are 28.96 (7) and 55.15 (7)°. The dihedral angles between the benzene rings and their attached acetyl-sulfanyl groups are 59.60 (10) and 84.79 (10)°. The expected π-π stacking inter-actions are not observed in the crystal structure; instead, the packing features C-H⋯O hydrogen bonds, which link the mol-ecules into C(12) [010] chains, which are supported by weak C-H⋯π contacts.

| S-EPMC4719999 | biostudies-literature

Di-?-hydroxido-bis-[tris-(4,4,4-trifluoro-1-phenyl-acetyl-acetonato-?O,O')hafnium(IV)] dimethyl-formamide disolvate.

Project description:The binuclear molecule of the title compound, [Hf(2)(C(10)H(6)F(3)O(2))(6)(OH)(2)]·2C(3)H(7)NO, lies across an inversion centre and contains a Hf(IV) atom which is eight-coordinated and surrounded by three chelating ?-diketonato tris-(4,4,4-trifluoro-1-phenyl-acetyl-acetonate (tfba(-)) ligands and two bridging OH(-) groups in a distorted square-anti-prismatic geometry. The Hf-O bond lengths vary from 2.073?(2) to 2.244?(2)?Å and the O-Hf-O bite angles vary from 73.49?(9) to 75.60?(9)°. Weak O-H?O hydrogen-bonding inter-actions are observed between the bridging hy-droxy groups and the dimethylformamide solvent mol-ecules. The unit cell contains solvent-accessible voids of 131?Å(3), but the residual electron density in the difference Fourier map suggests no solvent mol-ecule occupies this void.

| S-EPMC3238724 | biostudies-literature

Bis(acetyl-acetonato-?O,O')(pyridine-?N)zinc(II).

Project description:In the title compound, [Zn(C(5)H(7)O(2))(2)(C(5)H(5)N)], the metal atom has square-pyramidal coordination geometry with the basal plane defined by the four O atoms of the chelating acetyl-acetonate ligands and with the axial position occupied by the pyridine N atom. The crystal packing is characterized by a C-H?O hydrogen-bonded ribbon structure approximately parallel to [10[Formula: see text]].

| S-EPMC3120430 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data