Browse
Submit Data
Databases
API
Help

Dataset Information

5 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Bis(acetato-?O,O')(2,2':6',2''-terpyridine-?N,N',N'')manganese(II) dihydrate.

ABSTRACT: The Mn(II) ion in the title compound, [Mn(CH(3)CO(2))(2)(C(15)H(11)N(3))]·2H(2)O, is seven-coordinated in a considerably distorted penta-gonal-bipyramidal geometry by three N atoms of the tridentate 2,2':6',2''-terpyridine ligand and four O atoms from two acetate anions which chelate the Mn atom via two O atoms. The lateral pyridine rings are slightly inclined to the central pyridine ring, making dihedral angles of 13.6?(2) and 5.7?(2)°. The complex and solvent water mol-ecules are linked by inter-molecular O-H?O hydrogen bonds into a three-dimensional network.

SUBMITTER: Ha K

PROVIDER: S-EPMC3274864 | biostudies-other | 2012 Feb

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

Bis(acetato-κO,O')(2,2':6',2''-terpyridine-κN,N',N'')manganese(II) dihydrate.

Ha Kwang K

Acta crystallographica. Section E, Structure reports online 20120107 Pt 2

The Mn(II) ion in the title compound, [Mn(CH(3)CO(2))(2)(C(15)H(11)N(3))]·2H(2)O, is seven-coordinated in a considerably distorted penta-gonal-bipyramidal geometry by three N atoms of the tridentate 2,2':6',2''-terpyridine ligand and four O atoms from two acetate anions which chelate the Mn atom via two O atoms. The lateral pyridine rings are slightly inclined to the central pyridine ring, making dihedral angles of 13.6 (2) and 5.7 (2)°. The complex and solvent water mol-ecules are linked by int ...[more]

PMID: 22346811

Similar Datasets

?-Succinato-bis-[aqua-(2,2':6',2''-terpyridine)copper(II)] dinitrate dihydrate.

Project description:The title compound, [Cu(2)(C(4)H(4)O(4))(C(15)H(11)N(3))(2)(H(2)O)(2)](NO(3))(2)·2H(2)O, was synthesized under hydro-thermal conditions. The dinuclear copper complex is located on a crystallographic inversion centre. The Cu(II) ion is penta-coordinated in a tetra-gonal-pyramidal geometry, with one O atom of a succinate dianion and three N atoms of a 2,2':6',2''-terpyridine ligand occupying the basal plane, and a water O atom located at the apical site. In the crystal structure, O-H?O hydrogen bonding links the mol-ecules into a chain parallel to the a axis.

| S-EPMC2983631 | biostudies-literature

Bis(2,2'-bipyridine)(2-hy-droxy-2,2-diphenyl-acetato)-copper(II) nitrate dihydrate.

Project description:In the title complex, [Cu(C(14)H(11)O(3))(C(10)H(8)N(2))(2)]NO(3)·2H(2)O, the Cu(II) atom is coordinated by four N atoms from two 2,2'-bipyridine ligands and two O atoms from one benzilate ligand in a distorted octa-hedral geometry. A supra-molecular network is formed via inter-molecular O-H?O and C-H?O hydrogen-bonding inter-actions. ?-? stacking inter-actions between neighboring pyridine rings are also present, the centroid-centroid distance being 3.808?(2)?Å.

| S-EPMC2983227 | biostudies-literature

Bis(2,2'-bipyrid-yl)(dichloro-acetato)copper(II) dichloro-acetate dihydrate.

Project description:In the title compound, [Cu(C(2)HCl(2)O(2))(C(10)H(8)N(2))(2)](C(2)HCl(2)O(2))·2H(2)O, the Cu(II) ion is bonded to two N,N'-bidentate 2,2'-bipyridyl ligands and one O-monodentate 2,2-dichloro-acetate anion in a distorted CuON(4) trigonal-bipyramidal geometry, with the O atom occupying an equatorial site. In the crystal, the components are linked by O-H?O and O-H?Cl hydrogen bonds.

| S-EPMC2979737 | biostudies-literature

trans-Bis(acetato-?O)diaquabis-(2-amino-pyrazine-?N)manganese(II) dihydrate.

Project description:The Mn(II) atom in the title compound, [Mn(CH(3)COO)(2)(C(4)H(5)N(3))(2)(H(2)O)(2)]·2H(2)O, is situated on a center of inversion and shows an octa-hedral coordination polyhedron made up by four O atoms and two N atoms. The octa-hedron is somewhat tetra-gonally distorted owing to the longer Mn-N bond [2.323?(3)?Å]. The mononuclear complex mol-ecule and uncoordinated water mol-ecules are linked by O-H?N, N-H?O and O-H?O hydrogen bonds, generating a three-dimensional network.

| S-EPMC3212198 | biostudies-literature

Bis(?-2-phenyl-acetato-?O:O)bis-[(2,2'-bipyridyl-?N,N')(2-phenyl-acetato-?O)copper(II)] dihydrate.

Project description:The mol-ecule of the binuclear title complex, [Cu(2)(C(8)H(7)O(2))(4)(C(10)H(8)N(2))(2)]·2H(2)O, is located on an inversion centre. The Cu atoms are bridged by two O atoms of the monodentate phenyl-acetate groups [Cu-O = 1.9808?(14) and 2.3668?(14)?Å]. The longer of the two bridging Cu-O bonds takes the apical position of the distorted square-pyramidal environment of the Cu atom, which is completed by two N atoms of the chelate 2,2'-bipyridine ligand [Cu-N = 2.0107?(17) and 2.0234?(16)?Å]. The mol-ecules are assembled into stacks along [100] through ?-? inter-actions with inter-planar distances of 3.630?(4) and 3.407?(3)?Å; the resulting stacks are further connected into a three-dimensional supra-molecular architecture by O-H?O and C-H?O hydrogen-bonding inter-actions.

| S-EPMC3201355 | biostudies-literature

Bis(4'-chloro-2,2':6',2''-terpyridine-κN,N',N'')iron(II) dinitrate dihydrate.

Project description:The title complex, [Fe(C(15)H(10)ClN(3))(2)](NO(3))(2)·2H(2)O, has a six-coordinate iron(II) center balanced by two nitrate anions. The Fe atom lies on a twofold rotation axis. The complex exhibits an octa-hedral coordination configuration, where the dihedral angle between the two planar tridentate ligands is 92.4 (1)°. The crystal structure involves O-H⋯O hydrogen bonds.

| S-EPMC2914957 | biostudies-literature

cis-(Acetonitrile-?N)aqua-bis-(2,2'-bipyrimidine-?N,N)manganese(II) cis-diaqua-bis-(2,2'-bipyrimidine-?N,N)manganese(II) tetrakis(perchlorate) dihydrate.

Project description:The asymmetric unit of the title compound, [Mn(CH(3)CN)(C(8)H(6)N(4))(2)(H(2)O)][Mn(C(8)H(6)N(4))(2)(H(2)O)(2)](ClO(4))(4)·2H(2)O, contains two distinct cationic Mn(II) complexes, four perchlorate anions and two solvent water mol-ecules. In the two complexes, both Mn(II) ions are six-coordinated in a distorted octa-hedral environment, but one Mn ion has a cis-N(5)O coordination geometry defined by four N atoms of the two chelating 2,2'-bipyrimidine (bpym) ligands, one N atom of a coordinating acetonitrile mol-ecule and one O atom of a water ligand, whereas the other Mn ion has a cis-N(4)O(2) coordination geometry defined by four N atoms of the two bpym ligands and two O atoms of water ligands. In the crystal structure, the complex mol-ecules, anions and solvent water mol-ecules are linked by inter-molecular O-H?O and O-H?N hydrogen bonds. Three of the four perchlorate anions are disordered over two sets of sites in different ratios.

| S-EPMC3120370 | biostudies-literature

Bis(4'-chloro-2,2':6',2''-terpyridine-?(3)N,N',N'')ruthenium(II) dichloride dihydrate.

Project description:In the cation of the title compound, [Ru(C(15)H(10)ClN(3))(2)]Cl(2)·2H(2)O, the metal atom exhibits a distorted octa-hedral coordination geometry provided by the N atoms of two tridentate terpyridine ligands. The ligands are approximately planar [maximum deviation = 0.156?(5)?Å] and form a dihedral angle of 87.0?(3)°. In the crystal, the cations, anions and water mol-ecules are linked into a three-dimensional network by C-H?Cl, C-H?O and O-H?Cl hydrogen bonds.

| S-EPMC3379109 | biostudies-literature

Tetra-aqua-bis{2-[4-(3-pyrid-yl)pyrimidin-2-ylsulfan-yl]acetato}manganese(II) dihydrate.

Project description:In the title compound, [Mn(C(11)H(8)N(3)O(2)S)(2)(H(2)O)(4)]·2H(2)O, the Mn(II) ion lies on an inversion centre and is coordinated by four water mol-ecules in equatorial positions and two N atoms from two 2-[4-(3-pyrid-yl)pyrimidin-2-ylsulfan-yl]acetate ligands in the axial positions. The water mol-ecules, including the uncoordinated water mol-ecules, and the acetate O atoms are involved in O-H?O and O-H?N hydrogen-bonding inter-actions, which link the components into layers parallel to the a (b + c) plane.

| S-EPMC2970048 | biostudies-literature

Bis(2,2':6',2''-terpyridine)-ruthenium(II) bis-(perchlorate) hemihydrate.

Project description:The asymmetric unit of the title compound, [Ru(C(15)H(11)N(3))(2)](ClO(4))(2)·0.5H(2)O, contains one ruthenium-terpiridine complex cation, two perchlorate anions and one half-mol-ecule of water. Face-to-face and face-to-edge ?-stacking inter-actions between terpyridine units [centroid-centroid distances = 3.793?(2) and 3.801?(2)? Å] stabilize the crystal lattice The partially occupied water mol-ecule inter-acts with two perchlorate ions via O-H?O hydrogen bonds. In the crystal lattice, the complex cations, perchlorate ion-water pairs and the second perchlorate anions are arranged into columns along b direction.

| S-EPMC3515152 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data