Ontology highlight
ABSTRACT:
SUBMITTER: Zhang J
PROVIDER: S-EPMC3344417 | biostudies-other | 2012 May
REPOSITORIES: biostudies-other
Acta crystallographica. Section E, Structure reports online 20120428 Pt 5
In the title compound, [Ca(C(2)H(6)OS)(6)][W(6)O(19)], the cation and anion both have a crystallographically imposed centre of symmetry. The Ca(II) atom in the cation is coordinated by six O atoms from six dimethyl sulfoxide ligands in a distorted octa-hedral geometry. The [W(6)O(19)](2-) isopolyanion possesses the well-known Lindqvist structure in which each W(VI) atom is coordinated by four μ(2)-O, one terminal O and one μ(6)-O atom. ...[more]