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Di-?2-chlorido-bis-[chlorido(?(5)-2,3,4,5-tetra-methyl-1-propyl-cyclo-penta-dien-yl)iridium(III)].

ABSTRACT: The asymmetric unit of the title complex, [Ir2Cl4(C12H19)2], a versatile starting material for the preparation of uniquely substituted penta-alkyl-cyclo-penta-dien-yl-iridium complexes, consists of an iridium(III) atom, a substituted cyclo-penta-dienyl ligand and two chlorine ligands. The full dimer is generated by an inversion center. In the dimer, the two Ir(III) atoms and two bridging Cl atoms form a perfectly planar ring. The two Ir(III) atoms and the two terminal Cl atoms also form a rigorous plane that is orthogonal [89.48?(3)°] to the Ir2Cl2 ring. The plane of the cyclo-penta-dienyl ligand forms a dihedral angle of 54.06?(7)° with respect to the Ir2Cl2 ring.

SUBMITTER: Merola JS

PROVIDER: S-EPMC3588487 | biostudies-other | 2013 Mar

REPOSITORIES: biostudies-other

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Di-μ2-chlorido-bis-[chlorido(η(5)-2,3,4,5-tetra-methyl-1-propyl-cyclo-penta-dien-yl)iridium(III)].

Merola Joseph S JS Morris David D De Weerd Nicholas N

Acta crystallographica. Section E, Structure reports online 20130228 Pt 3

The asymmetric unit of the title complex, [Ir2Cl4(C12H19)2], a versatile starting material for the preparation of uniquely substituted penta-alkyl-cyclo-penta-dien-yl-iridium complexes, consists of an iridium(III) atom, a substituted cyclo-penta-dienyl ligand and two chlorine ligands. The full dimer is generated by an inversion center. In the dimer, the two Ir(III) atoms and two bridging Cl atoms form a perfectly planar ring. The two Ir(III) atoms and the two terminal Cl atoms also form a rigoro ...[more]

PMID: 23476515

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